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Oscillating trend of ionization energy i...

Oscillating trend of ionization energy is found in:

A

group 12

B

group 13

C

group 14

D

group 15

Text Solution

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The correct Answer is:
To solve the question regarding the oscillating trend of ionization energy, we will analyze the trends in different groups of the periodic table, particularly focusing on Group 13 (the Boron family). ### Step-by-Step Solution: 1. **Understanding Ionization Energy**: - Ionization energy is the energy required to remove the outermost electron from an atom. - Generally, as we move down a group in the periodic table, the size of the atoms increases, leading to a decrease in ionization energy because the outermost electron is further from the nucleus and experiences less nuclear attraction. 2. **Analyzing Group 12 (Zinc Family)**: - In Group 12, which includes Zinc (Zn), Cadmium (Cd), and Mercury (Hg), the trend is straightforward. - As we move down the group, the atomic size increases, and thus the ionization energy decreases. However, there is no oscillating trend here; it is a consistent decrease. 3. **Analyzing Group 13 (Boron Family)**: - In Group 13, which includes Boron (B), Aluminum (Al), Gallium (Ga), Indium (In), and Thallium (Tl), we observe a unique trend. - The expected trend would be a decrease in ionization energy as we move down the group due to increasing atomic size. However, due to the effects of d-electron shielding in Gallium, the ionization energy does not follow a simple decreasing trend. - The ionization energies for these elements show fluctuations: - B > Al (decrease) - Al < Ga (increase) - Ga > In (decrease) - In < Tl (increase) - This results in an oscillating trend where the ionization energy first decreases, then increases, and continues to oscillate. 4. **Conclusion**: - The oscillating trend of ionization energy is specifically observed in Group 13 (the Boron family). Therefore, the answer to the question is **Group 13**. ### Final Answer: The oscillating trend of ionization energy is found in **Group 13 (Boron Family)**.
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