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The negative value of electron gain enth...

The negative value of electron gain enthalpy is less for fluorine than for chlorine . Why?

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The correct Answer is:
A

Electron gain enthalpy of F is less than that of Cl because when an electron is added to F, the added electron goes to the smaller n=2 quantum level and suffers repulsion from other electrons present in this level.
In case of Cl, the added electrons goes to the larger n=3 quantum level and suffers much less repulstion from other electrons.
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Knowledge Check

  • Electron gain enthalpy is greater than zero for

    A
    `Na`
    B
    `Mg`
    C
    `A1`
    D
    `Sn`
  • The lower electron affinity of fluorine than that of chlorine is due to

    A
    Smaller size
    B
    Smaller nuclear charge
    C
    Difference in their electronic arrangement
    D
    Its highest reactivity
  • NCERT EXEMPLAR-CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES.-Short answer types questions
    1. The negative value of electron gain enthalpy is less for fluorine than...

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    2. All transition elements are d-block elements, but all d-block elements...

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    3. Identify the group nad valency of the elements having atomic number 11...

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    4. Ionisation enthalpies of elements of second period are given below Ion...

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    5. Among the elements, B, Al, C and Si, a) which element has the highes...

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    6. Describe the main characteristic properties of s, p, d and f-block ele...

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    7. Choose the correct order of atomic radii of fluorine and neon (in pm) ...

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    8. Illustrate by taking examples of transition elements and non-transitio...

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    9. Nitrogen has positive electron gain enthalpy whereas oxygen has negati...

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    10. First member of each group of representative elements (i.e., s and p-b...

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    11. p-block elements form acidic, basic and amphoteric oxides. Explanin ea...

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    12. How would you explain the fact that the first ionisation enthalpy of s...

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    13. What do you undestand by exothermic reaction and endothermic reaction?...

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    14. Arrange the elements N, P, O and S in the order of i) increasing fir...

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    15. Explain the deviation in ionsation enthalpy of some elements from the ...

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    16. Explain the following a) Electronegatively of elements increase on m...

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    17. How does the metallic and non-metalic character vary on moving from le...

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    18. The radius of Na^(+) cation is less than that of Na atom. Give reason.

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