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In the form of dichromate, Cr(VI) is a s...

In the form of dichromate, Cr(VI) is a strong oxidising agent in acidic medium but Mo(VI) in `Mo0_(3)` and W(VI) in `W0_(3)` are not because

A

Cr (VI) is more stable than Mo(VI) and W(VI).

B

Mo (VI) and W (VI) are more stable than Cr(VI).

C

Higher oxidation states of heavier members of group-6 of transition series are more stable.

D

Lower oxidation states of heavier members of group-6 of transition series are more satble.

Text Solution

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The correct Answer is:
B, C

In d-block elements, for heavier elements, the higher oxidation states are more stable. Hence, Mo(VI) and W(VI) are more stable than Cr (VI). That’s why, Cr (VI) in the form of dichromate is a stronger oxidising agent in acidic medium whereas `MoO_(3)` and `WO_(3)` are not.
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NCERT EXEMPLAR-D AND F-BLOCK ELEMENTS-D And F-Block Elements
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  2. Transition elements show magnetic moment due to spin and orbital motio...

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  3. In the form of dichromate, Cr(VI) is a strong oxidising agent in acidi...

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  4. Which of the following actinoids show oxidation states upto +7?

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  5. General electronic configuration of actinoids is (n-2)f^(1-14)(n-1)d^(...

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  6. Which of the following lanthanoids show +2 oxidation state besides the...

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  7. Which of the following ions show higher spin only magnetic moment va...

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  8. Transition elements form binary compounds with halogens. Which of the ...

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  9. Which of the following will not act as oxidising agents?

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  10. Although +3 is the characteristic oxidation state for lanthanoids but ...

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  11. Why does copper not replace hydrogen from acids?

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  12. Why E^(-) values for Mn, Ni and Zn are more negative than expected?

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  13. Why first ionisation enthalpy of Cr is lower than that of Zn?

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  14. Transition elements show high melting points. Why?

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  15. When Cu^(2+) ion is treated with KI, a white precipitate is formed. Ex...

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  16. Out of Cu(2)Cl(2) and CuCl(2), which is more stable and why?

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  17. When a brown compound of manganese (A) is treated with HCl it gives a ...

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  18. Although fluorine is more electronegative than oxygen, but the ability...

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  19. Although Cr^(3+) and Co^(2+) ions have same number of unpaired electro...

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  20. Ionisation enthalpies of Ce, Pr and Nd are higher than Th, Pa and U. W...

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