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Although +3 is the characteristic oxidat...

Although `+3` is the characteristic oxidation state for lanthanoids but cerium also shows `+4` oxidation state because

A

it has variable ionisation enthalpy

B

it has a tendency to attain noble gas configuration

C

it has a tendency to attain `f^(0)` configuration

D

it resembles `Pb^(4+)`

Text Solution

Verified by Experts

The correct Answer is:
B, C

Electronic configuration of `._(58)Ce = ._(54)[Xe]4f^(2)5d^(0)6s^(2)`.
Therefore, electronic configuration of `Ce^(4+)=._(54)[Xe]4f^(0)`.
Thus, it has a tendency to attain noble gas configuration and attain `f^(0)` configuration.
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Knowledge Check

  • Although +3 is the characteristics oxidation state for lanthanide yet cerium also shows +4 oxidation state because (I) it nhas a tendency to attain noble gas configuration (ii)it has variable ionisation enthalpy. (iii)it resembles Pb^(4+) (iv) it has a tendency to attain f^0 configuration The correct option is

    A
    I and IV
    B
    II, and IV
    C
    I and II
    D
    II and III
  • Although +3 is the characteristic oxidation state for lanthanide yst cerium also shows +4 oxidation state because I. It has a tendency to attain noble gas configuration. II. It has variable ionisation enthalpy. III. It has a tendency to attain f^0 configuration. The correct option is

    A
    I and II
    B
    II and III
    C
    I and II
    D
    Only II
  • The most characteristic oxidation state of lanthanide is

    A
    `+2`
    B
    `+3`
    C
    `+4`
    D
    `+6`
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