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Oxidation number of nitrogen can be -...

Oxidation number of nitrogen can be -

A

From + 5 to -3

B

From -5 to -3

C

From -5 to +3

D

From + 10 to +6

Text Solution

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The correct Answer is:
To determine the oxidation number of nitrogen and its possible range, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Atomic Number and Electron Configuration**: - The atomic number of nitrogen (N) is 7. - Its electronic configuration is 1s² 2s² 2p³. 2. **Determine Valence Electrons**: - Nitrogen has 5 valence electrons (2 in the 2s subshell and 3 in the 2p subshell). 3. **Assess Possible Oxidation States**: - Nitrogen can either gain or lose electrons to achieve a stable electronic configuration. - If nitrogen gains 3 electrons, it will have a total of 8 electrons in its outer shell (2s² 2p⁶), achieving a noble gas configuration. This results in an oxidation state of -3. - If nitrogen loses all 5 valence electrons, it will have a positive charge of +5. 4. **Examples of Oxidation States**: - In ammonia (NH₃), nitrogen has an oxidation state of -3. Here, hydrogen is +1, and since there are three hydrogens, the total contribution from hydrogen is +3, making nitrogen -3 to balance the overall charge to zero. - In nitric acid (HNO₃), nitrogen has an oxidation state of +5. Here, hydrogen is +1, and each oxygen is -2 (total of -6 from three oxygens). To balance the overall charge to zero, nitrogen must be +5. 5. **Conclusion on the Range of Oxidation States**: - Therefore, the oxidation number of nitrogen can vary from -3 to +5. ### Final Answer: The oxidation number of nitrogen can be -3, 0, +1, +2, +3, +4, or +5, with common states being -3 in ammonia and +5 in nitric acid. ---
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Knowledge Check

  • During the reduction of nitro compound to an amine the oxidation number of nitrogen changes by

    A
    six units
    B
    five units
    C
    four units
    D
    three units
  • In NH_(4)NO_(2) , the oxidation number of nitrogen will be

    A
    `+3`
    B
    `+5`
    C
    `-3` and +3
    D
    `+3` and +5
  • Oxidation number of nitrogen in which among the oxide of nitrogen is the lowest ?

    A
    Nitric oxide
    B
    Nitrous oxide
    C
    Nitrogen dioxide
    D
    Nitrogen trioxide
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