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In the following redox reaction Cu(OH)(2...

In the following redox reaction `Cu(OH)_(2) (s) + N_(2) H_(4)(aq) rarr Cu(s) + N_(2)(g)` number of mole of `Cu(OH)_(2)` reduced by one mol of `N_(2) H_(4)` is -

A

1

B

2

C

3

D

4

Text Solution

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The correct Answer is:
To solve the question regarding the number of moles of Cu(OH)₂ reduced by one mole of N₂H₄ in the redox reaction: **Given Reaction:** \[ \text{Cu(OH)}_2 (s) + \text{N}_2\text{H}_4 (aq) \rightarrow \text{Cu} (s) + \text{N}_2 (g) \] **Step 1: Identify Oxidation States** - For Cu(OH)₂: - Cu has an oxidation state of +2. - OH has an oxidation state of -1. - For N₂H₄: - Let the oxidation state of nitrogen be \( x \). - The equation for the oxidation state is: \[ 2x + 4(1) = 0 \] \[ 2x + 4 = 0 \] \[ 2x = -4 \] \[ x = -2 \] - Therefore, nitrogen in N₂H₄ has an oxidation state of -2. **Step 2: Determine Changes in Oxidation States** - Cu changes from +2 (in Cu(OH)₂) to 0 (in Cu). - N changes from -2 (in N₂H₄) to 0 (in N₂). **Step 3: Calculate Electrons Transferred** - For Cu: - Change: +2 to 0 means it gains 2 electrons (reduction). - For N: - Change: -2 to 0 means it loses 4 electrons (oxidation). **Step 4: Establish the Stoichiometry** - From the above, we see that: - 1 mole of N₂H₄ loses 4 electrons. - 1 mole of Cu(OH)₂ gains 2 electrons. - Therefore, to balance the electrons: - 2 moles of Cu(OH)₂ will be reduced by 1 mole of N₂H₄. **Final Answer:** The number of moles of Cu(OH)₂ reduced by one mole of N₂H₄ is **2 moles**. ---
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