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If the wavelength of K(alpha) radiation ...

If the wavelength of `K_(alpha)` radiation emitted an atom of atomic number Z = 41 is `lambda` , then the atomic number for an atom that emits `K_(alpha)` radiation with the wavelength `4lambda`, is

A

21

B

28

C

11

D

36

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The correct Answer is:
To solve the problem, we need to establish the relationship between the wavelength of K-alpha radiation and the atomic number of the atom. The relationship can be expressed mathematically as: \[ \frac{1}{\lambda} \propto (Z - 1)^2 \] Where \( \lambda \) is the wavelength and \( Z \) is the atomic number. ### Step 1: Establish the relationship for the first atom For the first atom with atomic number \( Z_1 = 41 \) and wavelength \( \lambda_1 = \lambda \): \[ \frac{1}{\lambda} \propto (Z_1 - 1)^2 \] ### Step 2: Establish the relationship for the second atom For the second atom that emits K-alpha radiation with wavelength \( \lambda_2 = 4\lambda \): \[ \frac{1}{4\lambda} \propto (Z_2 - 1)^2 \] ### Step 3: Set up the proportionality equations From the proportionality, we can write: \[ \frac{\lambda_2}{\lambda_1} = \frac{(Z_1 - 1)^2}{(Z_2 - 1)^2} \] Substituting the known values: \[ \frac{4\lambda}{\lambda} = \frac{(41 - 1)^2}{(Z_2 - 1)^2} \] This simplifies to: \[ 4 = \frac{40^2}{(Z_2 - 1)^2} \] ### Step 4: Cross-multiply to solve for \( Z_2 \) Cross-multiplying gives: \[ 4(Z_2 - 1)^2 = 1600 \] ### Step 5: Divide both sides by 4 Dividing both sides by 4: \[ (Z_2 - 1)^2 = 400 \] ### Step 6: Take the square root of both sides Taking the square root of both sides: \[ Z_2 - 1 = 20 \quad \text{or} \quad Z_2 - 1 = -20 \] Since atomic numbers cannot be negative, we take: \[ Z_2 - 1 = 20 \] ### Step 7: Solve for \( Z_2 \) Adding 1 to both sides gives: \[ Z_2 = 21 \] ### Final Answer The atomic number for the atom that emits K-alpha radiation with the wavelength \( 4\lambda \) is \( Z_2 = 21 \). ---
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