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According to the Bohr model , what deter...

According to the Bohr model , what determines the shortest wavelength in a given series of wavelength emitted by the atom ?

A

The quantum number `n_i` that identifies the higher energy level from which the electron falls into a lower energy level.

B

The quantum number `n_f` that identifies the lower energy level into which the electron falls from a higher energy level.

C

The ratio `n_f//n_i` where `n_f` is the quantum number that identifies the lower energy level into which the electron falls and `n_i` is the quantum number that identifies the higher level from which the electron falls .

D

The sum `n_f +n_f` of two quantum numbers, where `n_f` identifies the lower energy `n_i` identifies the higher level from which the electron falls .

Text Solution

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The correct Answer is:
To determine the shortest wavelength in a given series of wavelengths emitted by an atom according to the Bohr model, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Bohr Model**: The Bohr model describes the behavior of electrons in an atom, particularly how they transition between different energy levels. When an electron transitions from a higher energy level (initial state, \( n_i \)) to a lower energy level (final state, \( n_f \)), it emits a photon whose wavelength can be calculated. 2. **Wavelength Formula**: The relationship between the wavelength (\( \lambda \)) of the emitted photon and the energy levels is given by the formula: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right) \] where \( R \) is the Rydberg constant, \( n_i \) is the initial energy level, and \( n_f \) is the final energy level. 3. **Maximizing \( \frac{1}{\lambda} \)**: To find the shortest wavelength, we need to maximize the term \( \frac{1}{\lambda} \). This occurs when the term \( \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right) \) is maximized. 4. **Setting \( n_f \) to Infinity**: The maximum value of \( \frac{1}{n_f^2} \) occurs when \( n_f \) approaches infinity. In this case, \( \frac{1}{n_f^2} \) approaches 0, making the term \( \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right) \) equal to \( -\frac{1}{n_i^2} \). Thus, the equation simplifies to: \[ \frac{1}{\lambda} = R \left( 0 - \frac{1}{n_i^2} \right) = -\frac{R}{n_i^2} \] This indicates that as \( n_f \) approaches infinity, the wavelength \( \lambda \) becomes the shortest possible. 5. **Conclusion**: Therefore, the shortest wavelength in a given series is determined by the final energy level \( n_f \) being set to infinity. The initial energy level \( n_i \) only determines which series of spectral lines we are observing (e.g., Lyman, Balmer series, etc.). ### Final Answer: The shortest wavelength in a given series of wavelengths emitted by the atom is determined by setting the final energy level \( n_f \) to infinity.
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Knowledge Check

  • The shortest wavelength of Balmer series of H-atom is

    A
    `4/R`
    B
    `36/(5R)`
    C
    `1/R`
    D
    `3/(4R)`
  • According to the Bohr's model of hydrogen atom

    A
    total energy of the electron quantised
    B
    angular momentum of the electron is quantised and given as `sqrtl(l+1)cdoth/2pi`
    C
    Both (1) and (2)
    D
    None of the above
  • According to Bohr's atomic model

    A
    the electron radiates energy only when it jumps to inner orbit
    B
    an atom has heavy, positively charged nucleus
    C
    the electron can move in particular orbits
    D
    all of these
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