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When one mole of monatomic gas is mixed ...

When one mole of monatomic gas is mixed with one mole of a diatomic gas, the equivalent value of `gamma` for the mixture will be (vibration mode neglected)

A

`1.33`

B

`1.40`

C

`1.50`

D

`1.6`

Text Solution

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The correct Answer is:
To find the equivalent value of \( \gamma \) (gamma) for a mixture of one mole of a monatomic gas and one mole of a diatomic gas, we can follow these steps: ### Step 1: Identify the degrees of freedom - For a monatomic gas, the degrees of freedom \( F \) is 3. - For a diatomic gas (neglecting vibrational modes), the degrees of freedom \( F \) is 5. ### Step 2: Calculate \( C_V \) for each gas - The formula for \( C_V \) (specific heat at constant volume) is given by: \[ C_V = \frac{F}{2} R \] - For the monatomic gas: \[ C_{V, \text{monatomic}} = \frac{3}{2} R \] - For the diatomic gas: \[ C_{V, \text{diatomic}} = \frac{5}{2} R \] ### Step 3: Calculate the mixture's \( C_V \) - The total \( C_V \) for the mixture can be calculated using the formula: \[ C_{V, \text{mix}} = \frac{N_1 C_{V1} + N_2 C_{V2}}{N_1 + N_2} \] - Here, \( N_1 = 1 \) (monatomic gas), \( C_{V1} = \frac{3}{2} R \), \( N_2 = 1 \) (diatomic gas), \( C_{V2} = \frac{5}{2} R \). - Plugging in the values: \[ C_{V, \text{mix}} = \frac{1 \cdot \frac{3}{2} R + 1 \cdot \frac{5}{2} R}{1 + 1} = \frac{\frac{3}{2} R + \frac{5}{2} R}{2} = \frac{8/2 R}{2} = 2R \] ### Step 4: Calculate \( C_P \) for each gas - The formula for \( C_P \) (specific heat at constant pressure) is given by: \[ C_P = C_V + R \] - For the monatomic gas: \[ C_{P, \text{monatomic}} = \frac{3}{2} R + R = \frac{5}{2} R \] - For the diatomic gas: \[ C_{P, \text{diatomic}} = \frac{5}{2} R + R = \frac{7}{2} R \] ### Step 5: Calculate the mixture's \( C_P \) - Using the same formula for the mixture: \[ C_{P, \text{mix}} = \frac{N_1 C_{P1} + N_2 C_{P2}}{N_1 + N_2} \] - Plugging in the values: \[ C_{P, \text{mix}} = \frac{1 \cdot \frac{5}{2} R + 1 \cdot \frac{7}{2} R}{1 + 1} = \frac{\frac{5}{2} R + \frac{7}{2} R}{2} = \frac{12/2 R}{2} = 3R \] ### Step 6: Calculate \( \gamma \) for the mixture - Finally, \( \gamma \) is calculated using the formula: \[ \gamma = \frac{C_P}{C_V} \] - Substituting the values: \[ \gamma = \frac{3R}{2R} = \frac{3}{2} = 1.5 \] ### Final Answer The equivalent value of \( \gamma \) for the mixture is \( 1.5 \).
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