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Bond energy of F2 is 150 kJ mol^(-1). Ca...

Bond energy of `F_2` is 150 kJ `mol^(-1)`. Calculate the minimum frequency of photon to break this bond.

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To calculate the minimum frequency of a photon required to break the bond in the `F_2` molecule, we can follow these steps: ### Step 1: Convert Bond Energy from kJ/mol to J/molecule The bond energy of `F_2` is given as 150 kJ/mol. We need to convert this energy into joules per molecule. 1. **Convert kJ to J**: \[ 150 \text{ kJ/mol} = 150 \times 10^3 \text{ J/mol} = 150000 \text{ J/mol} \] 2. **Calculate energy per molecule**: To find the energy for one molecule, we divide the total energy by Avogadro's number (\(N_A \approx 6.022 \times 10^{23} \text{ molecules/mol}\)): \[ \text{Energy per molecule} = \frac{150000 \text{ J/mol}}{6.022 \times 10^{23} \text{ molecules/mol}} \approx 2.49 \times 10^{-19} \text{ J} \] ### Step 2: Use Planck's Equation to Find Frequency Planck's equation relates the energy of a photon to its frequency: \[ E = h \nu \] Where: - \(E\) is the energy of the photon, - \(h\) is Planck's constant (\(6.626 \times 10^{-34} \text{ J s}\)), - \(\nu\) is the frequency of the photon. Rearranging the equation to solve for frequency: \[ \nu = \frac{E}{h} \] ### Step 3: Substitute the Values Now we can substitute the energy we calculated and Planck's constant into the equation: \[ \nu = \frac{2.49 \times 10^{-19} \text{ J}}{6.626 \times 10^{-34} \text{ J s}} \approx 3.76 \times 10^{14} \text{ Hz} \] ### Final Answer The minimum frequency of a photon required to break the bond in `F_2` is approximately: \[ \nu \approx 3.76 \times 10^{14} \text{ Hz} \]
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Knowledge Check

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