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(A) 1 faraday = 96,500 coulomb. It is ...

(A) 1 faraday = 96,500 coulomb.
It is a charge of 1 mole electrons.
(R) 1 faraday charge liberates one gram equivalent of substance at an electrode.

A

Both (R) and (A) are true and reason is the correct explanation of assertion.

B

Both (R) and (A) are true but reason is not correct explanation of assertion

C

Assertion (A) is true but reason (R) is false

D

Assertion (A) and reason (R) both are false

Text Solution

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The correct Answer is:
B
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One gram equivalent of a substance is liberated at an electrode by :

Electrolysis is the process in which electrical energy is converted to chemical energy. In electrolytic cell, oxidation takes place at anode and reduction at cathode. Electrode process depends on the electrode taken for electrolysis. Amount of substance liberated at an electrode is directly propertional to the amount of charge passed through it. The mass of substance liberated at electrode is calculated using the following relation : m= ("ItE")/(96500) Here, E represents the equivalent mass and 96500 C is called the Faraday constant. Faraday (96500 C) is the charge of 1 mole electron, i.e., 6.023 xx 10^(23) electrons, it is used to liberate one gram equivalent of the substance. On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be :

The electric charge for electrode deposition of one gram equivalent of a substance is:

Electrolysis is the process in which electrical energy is converted to chemical energy. In electrolytic cell, oxidation takes place at anode and reduction at cathode. Electrode process depends on the electrode taken for electrolysis. Amount of substance liberated at an electrode is directly propertional to the amount of charge passed through it. The mass of substance liberated at electrode is calculated using the following relation : m= ("ItE")/(96500) Here, E represents the equivalent mass and 96500 C is called the Faraday constant. Faraday (96500 C) is the charge of 1 mole electron, i.e., 6.023 xx 10^(23) electrons, it is used to liberate one gram equivalent of the substance. Calculate the volume of gas liberated at the anode at STP during the electrolysis of a CuSO_(4) solution by a current of 1 A passed for 16 minutes and 5 seconds :

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