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Most stable radical is...

Most stable radical is

A

B

C

`CH_(2)=CHoverset(cdot)CH_(2)`

D

`CH_(2)=overset(cdot)CH.`

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The correct Answer is:
To determine which radical is the most stable among the given options, we will analyze the stability based on resonance and hyperconjugation effects. Here’s a step-by-step solution: ### Step 1: Identify the Radicals First, we need to identify the structures of the radicals given in the options. Each radical will have an unpaired electron, which is crucial for determining stability. **Hint:** Look for the carbon atoms that have an unpaired electron (dot) in their structure. ### Step 2: Analyze Resonance Next, we will check if the radicals can participate in resonance. Resonance occurs when there are multiple valid Lewis structures for a molecule, allowing the electron density to be delocalized. - **Radical A:** Has a double bond adjacent to the radical, allowing resonance. - **Radical B:** No resonance is possible as there are no adjacent double bonds. - **Radical C:** Similar to Radical A, it has a double bond adjacent to the radical, allowing resonance. - **Radical D:** No resonance is possible here as well. **Hint:** Identify which radicals have adjacent double bonds that can stabilize the unpaired electron through resonance. ### Step 3: Compare Resonance Structures For the radicals that can resonate (A and C), we will draw their resonance structures to see how many contributing structures can stabilize the radical. - **Radical A:** Can form several resonance structures, contributing to its stability. - **Radical C:** Also forms resonance structures, but we need to analyze how many are identical and how they compare to Radical A. **Hint:** Count the number of resonance structures and check if they are identical or not. ### Step 4: Analyze Hyperconjugation Next, we will consider hyperconjugation, which involves the interaction of the radical with adjacent C-H bonds. The more alkyl groups attached to the radical, the more stable it becomes due to hyperconjugation. - **Radical A:** Has multiple adjacent hydrogen atoms contributing to hyperconjugation. - **Radical C:** Also has adjacent hydrogen atoms, but we need to count them. **Hint:** Look at the number of adjacent hydrogen atoms (alpha hydrogens) that can stabilize the radical through hyperconjugation. ### Step 5: Determine the Most Stable Radical After analyzing resonance and hyperconjugation, we can conclude which radical is the most stable. - **Radical A and C** have resonance, but if Radical C has more identical resonance structures and more alpha hydrogens, it will be more stable than Radical A. - **Radicals B and D** do not have resonance and are less stable. **Conclusion:** Based on the resonance and hyperconjugation analysis, **Radical C** is the most stable radical. **Final Answer:** The most stable radical is **Option C**.

To determine which radical is the most stable among the given options, we will analyze the stability based on resonance and hyperconjugation effects. Here’s a step-by-step solution: ### Step 1: Identify the Radicals First, we need to identify the structures of the radicals given in the options. Each radical will have an unpaired electron, which is crucial for determining stability. **Hint:** Look for the carbon atoms that have an unpaired electron (dot) in their structure. ### Step 2: Analyze Resonance ...
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DINESH PUBLICATION-BASIC PRINCIPLES OF ORGANIC CHEMISTRY-REVISION QUESTIONS FROM COMPETITIVE EXAMS.
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  10. The IUPAC name of the following compound is :

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  11. The which is not used as gaseous fuel :

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  12. The petrol of octane number 80 has :

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  15. The correct IUPAC name of the following compound is : H(3)C-CH=under...

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