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Although Cr^(3+) and Co^(2+) ions have s...

Although `Cr^(3+)` and `Co^(2+)` ions have same number of unpaired electrons but the magnetic moment of `Cr^(3+)` is 3.87 B.M. and that of `Co^(2+)` is 4.87 B.M. Why ?

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To understand why the magnetic moments of `Cr^(3+)` and `Co^(2+)` ions differ despite having the same number of unpaired electrons, we can follow these steps: ### Step 1: Determine the electronic configurations - **Chromium (Cr)** has an atomic number of 24. The electronic configuration of neutral chromium is `[Ar] 3d^5 4s^1`. When it loses three electrons to form `Cr^(3+)`, the configuration becomes `[Ar] 3d^3`. - **Cobalt (Co)** has an atomic number of 27. The electronic configuration of neutral cobalt is `[Ar] 3d^7 4s^2`. When it loses two electrons to form `Co^(2+)`, the configuration becomes `[Ar] 3d^7`. ### Step 2: Count the number of unpaired electrons - In `Cr^(3+)` with the configuration `[Ar] 3d^3`, there are 3 unpaired electrons (one in each of the three 3d orbitals). ...
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Although Cr^(3+) and Co^(2+) ions have the same number of unpaired electrons but the magnetic moment of Cr^(3+) is 3.87 BM and that of Co^(2+) is 4.87 BM. Why?

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Knowledge Check

  • Although Cr^(3+) and Co^(2+) ions have same number of unpaired electrons but the magnetic moment of Cr^(3+) is 3.87 B.M . and that of Co^(2+) 4.87 B.M. because….

    A
    They have different no. of d electrons
    B
    They have same electronic but different orbital contribution
    C
    They have different electronic but same orbital contriguration
    D
    they are typical elements.
  • The number of unpaired electrons in Cr^(3+) ion is

    A
    3
    B
    5
    C
    4
    D
    1
  • Cr in [Cr(NH_3)_6] Br_3 has number of unpaired electron :

    A
    4
    B
    3
    C
    1
    D
    2
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