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Although +3 oxidation stae is thje chara...

Although +3 oxidation stae is thje characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why ?

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Cerium `(Z=58)` has electronic configuration `[Xe]4f^(1)5d^(1)6s^(2)`. By losing three electrons, `Ce^(3+)` ion has the configuration `[Xe]4f^(1)`. It has quite obviously an urge to get rid of `4f^(1)` electron as well to achieve a noble gas configuration. Therefore, it also shows `+4` oxidation state in its compounds.
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Although +3 oxidation state is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why ?

Although +3 oxidation state is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?

Knowledge Check

  • The most characteristic oxidation state of lanthanide is

    A
    `+2`
    B
    `+3`
    C
    `+4`
    D
    `+6`
  • The most characteristic oxidation state of lanthanides is :

    A
    `+2`
    B
    `+3`
    C
    `+4`
    D
    None
  • Although +3 is the characteristic oxidation state for lanthanoids but cerium also shows +4 oxidation state because

    A
    it has variable ionisation enthalpy
    B
    it has a tendency to attain noble gas configuration
    C
    it has a tendency to attain `f^(0)` configuration
    D
    it resembles `Pb^(4+)`
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