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The value of rate constant of a pseudo f...

The value of rate constant of a pseudo first order reaction

A

 depends on the concentration of reactants present in small amount

B

depends on the concentration of reactants present in excess

C

is independent of the concentration of reactants

D

 depends only on temperature

Text Solution

Verified by Experts

The correct Answer is:
A, B

Pseudo first order reaction is a chemical reaction in which rate of reaction depends upon concentration of cnly one reactant while concentration of another reactant has no effect on rate of reaction.
e.g.. hydrolysis of ethyl acetate in presence of excess of water
`CH_(3)COOC_(2)H_(5) + underset("excess")(H_(2)O) overset(H^(+)) to CH_(3)COOH+ C_(2)H_(5)OH`
`r = k [ CH_(3)COO C_(2)H_(5)]^(2) [H_(2)O]^(O)`
Excess `[H_(2)O]` can cause the independency of reaction on `H_(2)O`.
Hence, (a) is the correct choice.
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Knowledge Check

  • The value of rate of a pseudo first order reaction depends upon

    A
    the concentration of both the reactants present in the reaction
    B
    the concentration of the reactant present small amount
    C
    the concentration of the reactant present in excess
    D
    the value of `Delta H` of the reaction.
  • Rate constant in case of first order reaction is

    A
    inversely proportional to the concentration units
    B
    independent of concentration units
    C
    directly proportional to concentration units
    D
    inversely proportional to the square of concentration units.
  • Rate constant in case of first order reaction is

    A
    inversely proportional to the concentration units
    B
    Independent of concentration units
    C
    directly proportional to the concentration units
    D
    inversely proportional to the square of the concentration units
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