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In a reaction, aA+bBrarrcC+dD rate =...

In a reaction,
`aA+bBrarrcC+dD`
rate `=-1/a(d[A])/(dt)` , the - ve sign in it represents

A

The rate of reaction increases with time

B

The rate is negative for the reaction

C

The concentration of the reactant 'A' decreases during the reaction

D

The concentration of reactant 'A' increases in the reaction

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The correct Answer is:
To solve the question regarding the negative sign in the rate expression for the reaction \( aA + bBr \rightarrow cC + dD \), we will analyze the meaning of the rate of reaction and the role of reactants and products. ### Step-by-Step Solution: 1. **Understanding the Rate Expression**: The rate of reaction is given by the expression: \[ \text{Rate} = -\frac{1}{a} \frac{d[A]}{dt} \] Here, \([A]\) represents the concentration of reactant A, and \(d[A]/dt\) is the change in concentration of A with respect to time. 2. **Significance of the Negative Sign**: The negative sign in the rate expression indicates that the concentration of reactant A is decreasing over time. In chemical reactions, reactants are consumed to form products. Therefore, as the reaction progresses, the concentration of A diminishes. 3. **Graphical Interpretation**: If we were to plot the concentration of A against time, we would observe a downward slope, indicating that the concentration of A is decreasing. The negative sign in the rate expression mathematically represents this decrease. 4. **Conclusion**: The negative sign is not an indication of the rate being negative or that the reaction is unfavorable; rather, it signifies that the concentration of the reactant A is decreasing as the reaction proceeds. Thus, the correct interpretation is that the concentration of reactant A decreases during the reaction. ### Final Answer: The negative sign in the rate expression represents that the concentration of reactant A decreases during the reaction. ---
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AAKASH INSTITUTE-CHEMICAL KINETICS-EXERCISE
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  2. Unit of rate of a reaction is

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  3. For the reaction, 2N2O5rarr4NO2+O2 Select the correct statement

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  4. What is the unit of rate constant of n^(th) order of the reaction ?

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  5. (dx)/(dt)=K[A]^(0.5)[B]^(0.5)[C]^(0.5) . What will be the order of the...

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  6. H2+l2 rarr 2Hl (An elementary reaction) of second order If the volum...

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  7. In a certain reaction shown below, 4A +2B rarr3C If rate of format...

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  8. The rate of reaction is always equal to the rate constant. The order o...

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  9. For the reaction, H2O2+2H^++3l^(-) rarrl3^(-)+2H2O select the corr...

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  10. The value rate constant depends upon

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  11. 2A rarrC+D In this reaction, if we double the concentration of A, re...

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  12. In a zero order reaction , 20% of the reaction complete in 10 s. How m...

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  13. If the half - life of the first order reaction is 50 s, what be the va...

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  14. In a first order reaction , on plotting a graph between t(1//2) and co...

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  15. In data given below. {:(,[A],[B],"rate"),(,mol//L,mol//L,mol L ^(-1...

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  16. For certain first order reaction, 75% of the reaction complete in 30 m...

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  17. For zero order reaction , t(1//2) will be (A0 is the initial concentra...

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  18. In pseudo - order reactions

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  19. The depletion of ozone involves the following steps : Step 1 : O3und...

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  20. The half life for the zero order reaction will be

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