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Paramagnetism is a property due to the p...

Paramagnetism is a property due to the presence of unpaired electrons. In case of transition metals, as they contain unpaired contain unpaired electrons in the `(n-1)` d orbitals , most of the transition metal ions and their compounds are paramagnetic . Paramagnetism increases with increases in number of unpaired electrons. Magnetic moment is calculated from spin only formula
`mu=sqrt(n(n+2)) B.M n="number of unpaired electrons"`
Similarly the colour of the compounds of transition metals may be attributed to the presence of incomplete `(n-1)` d sub-shell. When an electron from a lower energy of d-orbitals is excited to a higher energy d-orbital, the energy of excitation corresponds to the frequency of light absorbed. This frequency generally lies in the visible region. The colour observed corresponds to complementary colour of the light observed. The frequency of the light absorbed is determined by the nature of the ligand.
Titanium shows magnetic moments of `1.73 BM` in its compound. What is the oxidation state of titanium in the compound?

A

`+1`

B

`+4`

C

`+3`

D

`+2`

Text Solution

Verified by Experts

The correct Answer is:
C
no. of unpaired electron`=1`
`Ti=(Ar)4s^(2)3d^(2)`
`Ti^(+3)` having `1` unpaired electron.
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Paramagnetism is a property due to the presence of unpaired electrons. In case of transition metals, as they contain unpaired contain unpaired electrons in the (n-1) d orbitals , most of the transition metal ions and their compounds are paramagnetic . Paramagnetism increases with increases in number of unpaired electrons. Magnetic moment is calculated from spin only formula' Vz mu=sqrt(n(n+2)) B.M n="number of unpaired electrons" Similarly the colour of the compounds of transition metals may be attributed to the presence of incomplete (n-1) d sub-shell. When an electron from a lower energy of d-orbitals is excited to a higher energy d-orbital, the energy of excitation corresponds to the frequency of light absorbed. This frequency generally lies in the visible region. The colour observed corresponds to complementry colour of the light obserbed. The frequency of the light absorbed is determined by the nature of the ligand. Which of the following pair of Compounds is expected to exhibit same colour in aqueous solution

Knowledge Check

  • Paramagnetism is a property due to the presence of unpaired electrons. In case of transition metals, as they contain unpaired contain unpaired electrons in the (n-1) d orbitals , most of the transition metal ions and their compounds are paramagnetic . Paramagnetism increases with increases in number of unpaired electrons. Magnetic moment is calculated from 'spin only formula' Vz mu=sqrt(n(n+2)) B.M n="number of unpaired electrons" Similarly the colour of the compounds of transition metals may be attributed to the presence of incomplete (n-1) d sub-shell. When an electron from a lower energy of d-orbitals is excited to a higher energy d-orbital, the energy of excitation corresponds to the frequency of light absorbed. This frequency generally lies in the visible region. The colour observed corresponds to complementry colour of the light obserbed. The frequency of the light absorbed is determined by the nature of the ligand. The colourless species is:

    A
    `VCl_(3)`
    B
    `VOSO_(4)`
    C
    `Na_(3)VO_(4)`
    D
    `[V(H_(2)O_(6))SO_(4)]`

  • Paramagnetism is a property due to the presence of unpaired electrons. In case of transition metals, as they contain unpaired contain unpaired electrons in the (n-1) d orbitals , most of the transition metal ions and their compounds are paramagnetic . Paramagnetism increases with increases in number of unpaired electrons. Magnetic moment is calculated from 'spin only formula' Vz mu=sqrt(n(n+2)) B.M n="number of unpaired electrons" Similarly the colour of the compounds of transition metals may be attributed to the presence of incomplete (n-1) d sub-shell. When an electron from a lower energy of d-orbitals is excited to a higher energy d-orbital, the energy of excitation corresponds to the frequency of light absorbed. This frequency generally lies in the visible region. The colour observed corresponds to complementry colour of the light obserbed. The frequency of the light absorbed is determined by the nature of the ligand. Identify the correct statement.

    A
    `Mn^(2+)` has the highest paramagnetism amongst the bivalentcation of the `I^(st)` transition series.
    B
    The coloured ions or compounds of transition elements are due to d-d transition and charge transfer spectrum.
    C
    In `3d` series the paramagnetic character first increase to maximum & then start decreasing.
    D
    None of these

  • Paramagnetism is a property due to the presence of unpaired electrons. In case of transition metals, as they contain unpaired electrons in the (n-1)d orbitals, most of the transition metal ions and their compounds are paramagnetic. Paramagnetism increases with increases in number of unpaired electrons. Magnetic moment is calculated from '"Spin only formula"' viz. mu = sqrt(n(n+2)) B.M. n = no . of unpaired electrons Similarly the colour of the compounds of transition metals may be attributed to the presence of incomplete (n-1)d subshell. When an electron from a lower energy of d-orbital is excited to a higher energy d-orbital, the energy of excitation corresponding to the frequency of light absorbed. This frequency generally lies in the visible region. The colour observed correponds to complementary colour of the light absorbed. The frequency of the light absorbed is determined by the nature of the ligand. Titanium shows magnetic moment of 1.7 BM in its compound. What is the oxidation state of titanium in the compound?

    A
    `+2`
    B
    `+1`
    C
    `+3`
    D
    `+4`

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    Paramagnetism is a property due to the presence of unpaired electrons. In case of transition metals, as they contain unpaired electrons in the (n-1)d orbitals, most of the transition metal ions and their compounds are paramagnetic. Paramagnetism increases with increases in number of unpaired electrons. Magnetic moment is calculated from '"Spin only formula"' viz. mu = sqrt(n(n+2)) B.M. n = no . of unpaired electrons Similarly the colour of the compounds of transition metals may be attributed to the presence of incomplete (n-1)d subshell. When an electron from a lower energy of d-orbital is excited to a higher energy d-orbital, the energy of excitation corresponding to the frequency of light absorbed. This frequency generally lies in the visible region. The colour observed correponds to complementary colour of the light absorbed. The frequency of the light absorbed is determined by the nature of the ligand. Which of the following pair of compounds is expected to exhibit same colour in aqueous solution.

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