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A solution is 25% ethanol ans 50% acetic...

A solution is 25% ethanol ans 50% acetic acid by mass. Calculate the mole fraction of ethanol and acetic acid in the solution.

Text Solution

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Let us start with 100 g of the solutioon in which
Mass of water =25g
Mass of ethanol=25g
Mass of acetic acid = 50g
`n_(H_(2)O)=((25g))/((18gmol^(-1)))=1.388mol`
`n_(C_(2)H_(5)OH)=((25g))/((46gmol^(-1)))=0.543 mol`
`n_(CH_(3)COOH)=((50g))/((60gmol^(-1)))=0.833mol`
Total number of moles =(1,388+0.543+0.833)=2.764 mole
`x_(C_(2)COOH)" "=n_(C_(2)H_(5)OH)=((0.543 mol))/((2.764 mol))=0.196`
`x_(CH_(3)COOH)" "n_(CH_(3)COOH)=((0.833 mol))/((2.764 mol))=0.301`
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Knowledge Check

  • A solution has 25% of water, 25% ethanol and 50% acetic acid by mass. Calculate the mol e fraction of each component.

    A
    ` 0.50, 0.3, 0.19 `
    B
    ` 0.19,0.3,0.50 `
    C
    ` 0.3, 0.19, 0.50 `
    D
    ` 0.50, 0.19, 0.3 `
  • Rectified spirit contains 95% ethanol by mass. The mole fraction of ethanol will be

    A
    0.881
    B
    0.99
    C
    0.118
    D
    0.81
  • The percentage of carbon in acetic acid is

    A
    40
    B
    33.3
    C
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    D
    20
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