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Let us consider a binary solution of two...

Let us consider a binary solution of two volatile liquids 'A' and B, when taken in a closed container.Both the components would evaporate and an equilibrium would be established between vapour phase and liquid phase .Let the total pressure at this stage be `p_("total")` and `p_A` and `p_B` are partial pressures of A and B. Mole fractions of these components in liquid solution are `x_A` and `x_B`, that of vapour phase and `y_A` and `y_B` respectively `p_A^@` and `p_B^@` are vapour pressure of pure A & pure B .
Ideal liquid solution follow Raoult's law and non ideal liquid - liquid solution does not follow Raoult's law, deviation is measured in term of activity coefficient `gamma`
`gamma=p_("real")/p_("ideal")`

For water + alcohol solution correct set is :

A

(ii)(b)(Q)

B

(ii)(c )(R)

C

(iv)(d)(S)

D

(iv)(c )(R)

Text Solution

Verified by Experts

The correct Answer is:
B

water+alcohol`to` non ideal solution with +ve derivation correct code for this solution are (ii),(iv),b,c,d,Q,S
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Knowledge Check

  • Let us consider a binary solution of two volatile liquids 'A' and B, when taken in a closed container.Both the components would evaporate and an equilibrium would be established between vapour phase and liquid phase .Let the total pressure at this stage be p_("total") and p_A and p_B are partial pressures of A and B. Mole fractions of these components in liquid solution are x_A and x_B , that of vapour phase and y_A and y_B respectively p_A^@ and p_B^@ are vapour pressure of pure A & pure B . Ideal liquid solution follow Raoult's law and non ideal liquid - liquid solution does not follow Raoult's law, deviation is measured in term of activity coefficient gamma gamma=p_("real")/p_("ideal") For Hexane + neptane solution correct set is :

    A
    (i)(a)(Q)
    B
    (ii)(b)(P)
    C
    (ii)(d)(R)
    D
    (i)(d)(P)
  • Let us consider a binary solution of two volatile liquids 'A' and B, when taken in a closed container.Both the components would evaporate and an equilibrium would be established between vapour phase and liquid phase .Let the total pressure at this stage be p_("total") and p_A and p_B are partial pressures of A and B. Mole fractions of these components in liquid solution are x_A and x_B , that of vapour phase and y_A and y_B respectively p_A^@ and p_B^@ are vapour pressure of pure A & pure B . Ideal liquid solution follow Raoult's law and non ideal liquid - liquid solution does not follow Raoult's law, deviation is measured in term of activity coefficient gamma gamma=p_("real")/p_("ideal") For water + H_2SO_4 solution correct set is

    A
    (i)(a)(P)
    B
    (ii)(b)(Q)
    C
    (iii)(d)(R)
    D
    (iv)(c )(P)
  • If x_(1) and x_(2) represent the mole fraction of a component A in the vapour phase and liquid mixture respectively and p_(A)^(@) and p_(B)^(@) represent vapours pressures of pure A and pure B. then total vapour pressure of the liquid mixture is

    A
    `(p_(A)^(@)-x_(1))/(x_(2))`
    B
    `(p_(A)^(@)-x_(2))/(x_(1))`
    C
    `(p_(B)^(@)x_(1))/(x_(2))`
    D
    `(p_(B)^(@)x_(2))/(x_(1))`
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