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For sodium light, the two yellow lines o...

For sodium light, the two yellow lines occur at `lambda_(1) and lambda_(2)` wavelengths. If the mean of these two is `6000Å` and `|lambda_(2)-lambda_(1)|=6Å`, then the approximate energy difference between the two levels corresponding to `lambda_(1) and lambda_(2)` is

A

`2xx10^(-3)eV`

B

`2eV`

C

`2000eV`

D

`2xx10^(-6)eV`

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The correct Answer is:
To solve the problem, we need to find the approximate energy difference between two energy levels corresponding to the wavelengths \( \lambda_1 \) and \( \lambda_2 \) of sodium light. ### Step-by-Step Solution: 1. **Understanding the Mean Wavelength**: Given that the mean of the two wavelengths is \( 6000 \, \text{Å} \): \[ \frac{\lambda_1 + \lambda_2}{2} = 6000 \, \text{Å} \] This implies: \[ \lambda_1 + \lambda_2 = 12000 \, \text{Å} \quad \text{(Equation 1)} \] 2. **Understanding the Difference in Wavelengths**: We are also given that the difference between the two wavelengths is: \[ |\lambda_2 - \lambda_1| = 6 \, \text{Å} \] This gives us: \[ \lambda_2 - \lambda_1 = 6 \, \text{Å} \quad \text{(Equation 2)} \] 3. **Solving the Equations**: We can solve these two equations simultaneously. From Equation 2, we can express \( \lambda_2 \) in terms of \( \lambda_1 \): \[ \lambda_2 = \lambda_1 + 6 \] Substituting this into Equation 1: \[ \lambda_1 + (\lambda_1 + 6) = 12000 \] Simplifying this: \[ 2\lambda_1 + 6 = 12000 \] \[ 2\lambda_1 = 11994 \] \[ \lambda_1 = 5997 \, \text{Å} \] Now substituting back to find \( \lambda_2 \): \[ \lambda_2 = 5997 + 6 = 6003 \, \text{Å} \] 4. **Calculating the Energy Difference**: The energy corresponding to a wavelength \( \lambda \) is given by: \[ E = \frac{hc}{\lambda} \] Therefore, the energy difference \( \Delta E \) between the two wavelengths is: \[ \Delta E = E_1 - E_2 = \frac{hc}{\lambda_1} - \frac{hc}{\lambda_2} \] Factoring out \( hc \): \[ \Delta E = hc \left( \frac{1}{\lambda_1} - \frac{1}{\lambda_2} \right) \] This can be rewritten as: \[ \Delta E = hc \cdot \frac{\lambda_2 - \lambda_1}{\lambda_1 \lambda_2} \] 5. **Substituting Values**: Now substituting \( \lambda_1 = 5997 \, \text{Å} \), \( \lambda_2 = 6003 \, \text{Å} \), and \( \lambda_2 - \lambda_1 = 6 \, \text{Å} \): \[ \Delta E = hc \cdot \frac{6 \times 10^{-10}}{(5997 \times 10^{-10})(6003 \times 10^{-10})} \] Using \( h = 6.63 \times 10^{-34} \, \text{J s} \) and \( c = 3 \times 10^8 \, \text{m/s} \): \[ \Delta E = (6.63 \times 10^{-34})(3 \times 10^8) \cdot \frac{6 \times 10^{-10}}{(5997 \times 6003) \times 10^{-20}} \] 6. **Calculating the Final Value**: Calculate \( \Delta E \) and convert it to electron volts by dividing by \( 1.6 \times 10^{-19} \): \[ \Delta E \approx 2 \times 10^{-3} \, \text{eV} \] ### Final Answer: The approximate energy difference between the two levels corresponding to \( \lambda_1 \) and \( \lambda_2 \) is \( 2 \times 10^{-3} \, \text{eV} \).
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