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The shape around the central form in ClF...

The shape around the central form in `ClF_(4)^(+)` is

A

square planar

B

square pyramidal

C

octahedral

D

see - saw

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AI Generated Solution

The correct Answer is:
To determine the shape of the central atom in \( \text{ClF}_4^+ \), we can follow these steps: ### Step 1: Determine the Valence Electrons - Chlorine (Cl) has 7 valence electrons. - The \( \text{ClF}_4^+ \) ion has a positive charge, which means it has lost one electron. - Therefore, the total number of valence electrons for \( \text{ClF}_4^+ \) is \( 7 - 1 = 6 \) electrons. **Hint:** Remember to account for the charge when calculating the total number of valence electrons. ### Step 2: Identify the Number of Bonding Pairs and Lone Pairs - In \( \text{ClF}_4^+ \), chlorine is bonded to 4 fluorine atoms, which means there are 4 bonding pairs. - Since we have 6 total electrons and 4 are used for bonding, we have \( 6 - 4 = 2 \) electrons left. - These 2 remaining electrons will form 1 lone pair. **Hint:** Count the bonding pairs first, then subtract from the total valence electrons to find lone pairs. ### Step 3: Determine the Steric Number - The steric number is the sum of the number of bonding pairs and lone pairs. - Here, we have 4 bonding pairs and 1 lone pair, giving us a steric number of \( 4 + 1 = 5 \). **Hint:** The steric number helps in determining the hybridization and geometry of the molecule. ### Step 4: Identify the Hybridization - A steric number of 5 corresponds to \( \text{sp}^3\text{d} \) hybridization. **Hint:** Remember that hybridization can be determined from the steric number. ### Step 5: Determine the Molecular Geometry - With \( \text{sp}^3\text{d} \) hybridization and 1 lone pair, the molecular geometry is derived from the arrangement of the bonding pairs and lone pairs. - The arrangement of 4 bonding pairs and 1 lone pair leads to a seesaw shape (derived from a trigonal bipyramidal arrangement). **Hint:** Visualize the arrangement of atoms and lone pairs in three-dimensional space to determine the shape. ### Conclusion The shape around the central atom in \( \text{ClF}_4^+ \) is **seesaw**.
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Knowledge Check

  • The bond angle around the central atom is highest in

    A
    `B Br_3`
    B
    `CS_2`
    C
    `SO_2`
    D
    `SF_4`
  • The smallest bond angle around the central atom will be there in

    A
    `H_2O`
    B
    `BeF_2`
    C
    `CH_4`
    D
    `NH_3`
  • Which species has the same electron distribution around the central atom as SiF_(4) ?

    A
    `SF_(4)`
    B
    `XeF_(4)`
    C
    `ClF_(4)^(+)`
    D
    `BF_(4)^(-)`
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