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Select the correct plot of radial proba...

Select the correct plot of radial probability function `(4pir^(2)R^(2))` for 2s - orbital.

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B

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D

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The correct Answer is:
B
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The Schrodinger wave equation for H-atom is nabla^(2) Psi = (8pi^(2)m)/(h^(2)) (E-V) Psi = 0 Where nabla^(2) = (del^(2))/(delx^(2)) +(del^(2))/(dely^(2)) +(del^(2))/(delz^(2)) E = Total energy and V=potential energy wave function Psi_(((r, theta,phi)))R_((r))Theta_((theta))Phi_((phi)) R is radial wave function which is function of ''r'' only, where r is the distance from nucleus. Theta and Phi are angular wave function. R^(2) is known as radial probability density and 4pir^(2)R^(2)dr is known as radial probability function i.e., the probability of finding the electron is spherical shell of thickness dr. Number of radial node =n -l - 1 Number of angular node = l For hydrogen atom, wave function for 1s and 2s-orbitals are: Psi_(1s) = sqrt((1)/(pia_(0)^(a)))e^(-z_(r)//a_(0)) Psi_(2s) = ((Z)/(2a_(0)))^(½) (1-(Zr)/(a_(0)))e^(-(Zr)/(a_(0))) The plot of radial probability function 4pir^(2)R^(2) aganist r will be: Answer the following questions: The value of radius 'r' for 2s atomic orbital of H-atom at which the radial node will exist may be given as:

The Schrodinger wave equation for H-atom is nabla^(2) Psi = (8pi^(2)m)/(h^(2)) (E-V) Psi = 0 Where nabla^(2) = (del^(2))/(delx^(2)) +(del^(2))/(dely^(2)) +(del^(2))/(delz^(2)) E = Total energy and V=potential energy wave function Psi_(((r, theta,phi)))R_((r))Theta_((theta))Phi_((phi)) R is radial wave function which is function of ''r'' only, where r is the distance from nucleus. Theta and Phi are angular wave function. R^(2) is known as radial probability density and 4pir^(2)R^(2)dr is known as radial probability function i.e., the probability of finding the electron is spherical shell of thickness dr. Number of radial node =n -l - 1 Number of angular node = l For hydrogen atom, wave function for 1s and 2s-orbitals are: Psi_(1s) = sqrt((1)/(pia_(0)^(a)))e^(-z_(r)//a_(0)) Psi_(2s) = ((Z)/(2a_(0)))^(½) (1-(Zr)/(a_(0)))e^(-(Zr)/(a_(0))) The plot of radial probability function 4pir^(2)R^(2) aganist r will be: Answer the following questions: What will be number of angular nodes and spherical nodes for 4f atomic orbitals respectively.

Knowledge Check

  • Which of the following plots of radial - probability function 4pi^(2)psi^(2) is /are correct

    A
    Only i
    B
    ii and iii
    C
    I and iii
    D
    all

  • Which of the following plots of radical probability function 4pi r^(2)Psi_(r)^(2) is incorrectly labelled ?

    A
    B
    C
    D

  • The Schrodinger wave equation for H-atom is nabla^(2) Psi = (8pi^(2)m)/(h^(2)) (E-V) Psi = 0 Where nabla^(2) = (del^(2))/(delx^(2)) +(del^(2))/(dely^(2)) +(del^(2))/(delz^(2)) E = Total energy and V=potential energy wave function Psi_(((r, theta,phi)))R_((r))Theta_((theta))Phi_((phi)) R is radial wave function which is function of ''r'' only, where r is the distance from nucleus. Theta and Phi are angular wave function. R^(2) is known as radial probability density and 4pir^(2)R^(2)dr is known as radial probability function i.e., the probability of finding the electron is spherical shell of thickness dr. Number of radial node =n -l - 1 Number of angular node = l For hydrogen atom, wave function for 1s and 2s-orbitals are: Psi_(1s) = sqrt((1)/(pia_(0)^(a)))e^(-z_(r)//a_(0)) Psi_(2s) = ((Z)/(2a_(0)))^(½) (1-(Zr)/(a_(0)))e^(-(Zr)/(a_(0))) The plot of radial probability function 4pir^(2)R^(2) aganist r will be: Answer the following questions: The following graph is plotted for ns-orbitals The value of 'n' will be:

    A
    1
    B
    2
    C
    3
    D
    4

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