At `25^(@)` the specific conductance of a saturated solution of AgCl after subtracting the specific conducatnce of water is `1.82 xx 10^(4) Sm^(-1)`. The molar conductance at infinite dilution of `AgNO_(3), HNO_(3)` and HCl are respectively `133.0 xx 10^(-4), 421.0 xx 10^(-4) and 426 xx 10^(-4) S m^(2) "mol"^(-1)`. Find the solubility of AgCl. Write down the half cell reaction and calculate standard reduction potential for that the half Pt | 50mL 0.5 M KCl solution in which few drops of 0.1 M `E_(Ag, Ag)^(0)=0.80V.`

Answer

`1.32 xx 10^(-5)" mol dm"^(-3)`
0.224 V
Half cell reactions
`AgCl(s)+e^(-) to Ag(s)+Cl^(-) (aq)`