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The magnetic moment of [Mn(CN)(6)]^(3-) ...

The magnetic moment of `[Mn(CN)_(6)]^(3-)` is 2.8 B.M and that of `[MnBr_(4)]^(2-)`is 5.9 B.M. What are the geometries of these complex ions

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To determine the geometries of the complex ions \([Mn(CN)_6]^{3-}\) and \([MnBr_4]^{2-}\), we will analyze the magnetic moments and oxidation states of manganese in both complexes. ### Step 1: Analyze the magnetic moment of \([Mn(CN)_6]^{3-}\) 1. **Given Magnetic Moment**: The magnetic moment of \([Mn(CN)_6]^{3-}\) is 2.8 B.M. 2. **Magnetic Moment Formula**: The formula for magnetic moment (\(\mu\)) is given by: \[ \mu = \sqrt{n(n + 2)} ...
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FIITJEE-TRANSITION ELEMENTS & COORDINATION COMPOUNDS-SOLVED PROBLEMS(SUBJECTIVE)
  1. A metal complex having composition Cr(NH(3))(4)CI(2) Br has been isola...

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  2. Draw the structures of [Co(NH(3))(6)]^(3+) [Ni(CN)(4)]^(2-) and [Ni(CO...

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  3. The magnetic moment of [Mn(CN)(6)]^(3-) is 2.8 B.M and that of [MnBr(4...

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  4. Why chelated complexes are more stable than unchelated complexes

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  5. The hexaaqua complex[Ni(H(2)O)(6)]^(2+) is green, whereas the correspo...

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  6. Calculate magnetic moment of Fe^(3+) in [Fe(CN)(6)]^(3+) and in [Fe(H(...

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  7. Give the formula of three ions which are coloured due to charge transf...

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  8. Classify each of the following complexes as either high or low spin. E...

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  9. How do you account for the indicated molecular geometry for the follow...

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  10. An aqueous solution of CoCl(3).6NH(3) is found to be a better conducto...

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  11. Account for the following: Co(ll) is stable in aqueous solution but in...

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  12. The compounds of Zn, Cd and Hg are usually white. (ii) A dark blue pr...

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  13. A, B and C are three complexes of chromium(III) with empirical formula...

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  14. [NiC(4)]^(2-)It is paramagnetic while Ni[CO(4)] is diamagnetic though ...

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  15. Identify the complexes expected to be coloured and explain Ti(NO(3))(4...

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  16. Give evidence that [Co(NH(3))(5) CI] SO(4) Clare ionization isomers

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  17. Nicl(4)]^(2-) is paramagnetic while [Ni(CO(4))] is diamagnetic though ...

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  18. [Fe(H(2)O(6)]^(3+) is strongly paramagnetic whereas [Fe(CN)(6)]^(3-) i...

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  19. Explain (Co(NH(3))(6)]^(3+) is an inner orbital complex whereas [NI(NH...

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  20. Draw the structure of optical isomers of (i) [PICl(2)] (en)(2)]^(2+) ...

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