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What are ambident nucleophiles? Explain ...

What are ambident nucleophiles? Explain with an example.

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Nucleophiles which can attack through two different sites, are called ambident nucleophiles. For example, cyanide ion exists as a hydrid of following two structures. It can attack either.

Through carbon to form cyanides (or nitriles) or through nitrogen to form isocyanides (or carbyl amines).
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DINESH PUBLICATION-HALOALKANES AND HALOARENES-NCERT
  1. Give the iUPAC names of the following compounds: (i). CH(3)CH(Cl)CH(...

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  2. Write the structure sof the following compounds: (i). 2-Chloro-3-met...

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  3. Which one of the following has the highest dipole moment? (i) CH(2)C...

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  4. A hydrocarbon C(5)H(10) does not react with chlorine in dark but gives...

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  5. Write the isomers of the compound having formula C(4)H(9)Br.

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  6. Write the equations for the preparation of 1-iodobutane from (i) 1-b...

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  7. What are ambident nucleophiles? Explain with an example.

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  8. Which compound in the following pairs will react faster in SN^(2) reac...

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  9. Predict all the alkenes that would be formed by dehydrohalogenation of...

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  10. How will you bring about the following conversions? (i). Ethanol to ...

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  11. Explain: (i) Dipole moment of chlorobenzene is lower than that of cycl...

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  12. Write the structures of the major products in each of the following re...

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  13. Explain the following reaction: nBuBr+KCNoverset("Et-OH"//H(2)O)tonB...

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  14. Arrange the compound of each set in order of decreasing reactivity tow...

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  15. Out of C(6)H(5)CH(2)Cl and C(6)H(5)CHClC(6)H(5), which is more easily ...

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  16. p-Dichlorobenzene has higher m.p. than those of o- and m-isomers. Disc...

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  17. How the following conversions can be carried out? (i). Propene to pr...

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  18. The treatment of alkyl chlorides with aqueous KOH leads to the formati...

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  19. Primary alkyl halide (a) C(4)H(9)Br was reacted with alcoholic KOH to ...

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  20. What happens when (i) n-butyl chloride is treated with alcoholic KOH...

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