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Two substances P(4) &O(2) are allowed to...

Two substances `P_(4)` &`O_(2)` are allowed to react completely to form mixture of `P_(4)O_(6)` &`P_(4)O_(10)` leaving none of the reactants .Using this information calculate the moles of `P_(4)O_(6)` and `P_(4)H_(10)` in the final mixture when the following amounts of `P_(4)` & `O_(2)` are taken.
`P_(4) + 3O_(2) to P_(4)O_(6)`
`P_(4) + 5O_(2) to P_(4)O_(10)`
(i) If 1 mole `P_(4)` & 4 mole of `O_(2)`
(ii) If 3 mole `P_(4)` & 11 mole of `O_(2)`
(iii) If 3 mole `P_(4)` & 13 mole of `O_(2)`

Text Solution

Verified by Experts

The correct Answer is:
`(i)0.5,0.5;(ii)2,1(iii)1,2`
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Knowledge Check

  • In P_(4)O_(10) ,

    A
    second bond in P=O is formed by `ppi-dpi` back bonding
    B
    P=O bond is formed by `ppi-ppi` bonding
    C
    P=O bond is formed by `dpi-dpi` bonding
    D
    P=O bond is formed by `dpi-dpi-3 sigma` back bonding
  • P_(4)O_(10) is an anhydride of :

    A
    `H_(3)PO_(2)`
    B
    `H_(3)PO_(3)`
    C
    `H_(3)PO_(4)`
    D
    `H_(4)P_(2)O_(7)`
  • P_(4)O_(10) is the anhydride of the following

    A
    `H_(3)PO_(2)`
    B
    `H_(3)PO_(3)`
    C
    `H_(3)PO_(4)`
    D
    `H_(3)PO_(5)`
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