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In Friedel - Crafts reaction, AlCl(3) is...

In Friedel - Crafts reaction, `AlCl_(3)` is an electrophile.

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### Step-by-Step Solution 1. **Understanding Friedel-Crafts Reaction**: The Friedel-Crafts reaction is a type of electrophilic aromatic substitution where an aromatic compound (like benzene) reacts with an alkyl halide (like CH3Cl) in the presence of a catalyst. 2. **Role of AlCl3**: In this reaction, aluminum chloride (AlCl3) acts as a catalyst. It is classified as a Lewis acid because it can accept an electron pair. 3. **Formation of Electrophile**: AlCl3 coordinates with the alkyl halide (e.g., CH3Cl). This coordination leads to the formation of a carbocation (CH3+) which is the actual electrophile that will react with the benzene. 4. **Mechanism of Reaction**: - The benzene ring, being electron-rich, attacks the carbocation (CH3+). - This results in the formation of a new carbon-carbon bond between the benzene and the methyl group. - During this process, a hydrogen atom from the benzene is removed, forming HCl and an AlCl4- ion. 5. **Final Products**: The final products of the reaction are toluene (the methylated benzene), HCl, and AlCl3 (which can regenerate in the reaction). 6. **Conclusion**: The statement that "AlCl3 is an electrophile" is false. Instead, AlCl3 acts as a catalyst and facilitates the generation of the electrophile (the carbocation) from the alkyl halide.
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Friedel Craft Reaction

Assertion: Aniline does not undergo Friedel Crafts reaction. Reason : Friedel Crafts reaction is an electrophilic substitution reaction.

Knowledge Check

  • Assertion: Aniline does not undergo Friedel Crafts reaction. Reason : Friedel Crafts reaction is an electrophilic substiution reaction.

    A
    Assertion and reason both are both wrong statements .
    B
    Assertion is correct statement but reason is wrong statement
    C
    Assertion is wrong statement but reason is correct statement
    D
    Assertion and reason both are correct statements but reasson is not correct explanation of assertion
  • (A) Nitrobenzene undergoes Friedel-Craft reaction. (R) Friedel-Crafts reaction is an electrophilic substitution reaction.

    A
    If both A and R are correct and R is the correct explanation of A.
    B
    If both A and R are correct and R is not the correct explanation of A.
    C
    If A is the correct but R is incorect.
    D
    If A is the incorrect but R is corect.
  • In the Friedel-Crafts acylation reaction, the electrophile is

    A
    `R^(+)`
    B
    `R-overset(+)(C)=O`
    C
    `R-overset(.)(C)=O`
    D
    `R-underset(Cl)underset(|)overset(.)(C)-O-overline(A)lCl_(3)`
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