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Electrolysis is the process in which ele...

Electrolysis is the process in which electrical energy is converted to chemical energy. In electrolytic cell, oxidation takes place at anode and reduction at cathode. Electrode process depends on the electrode taken for electrolysis. Amount of substance liberated at an electrode is directly propertional to the amount of charge passed through it. The mass of substance liberated at electrode is calculated using the following relation :
`m= ("ItE")/(96500)`
Here, E represents the equivalent mass and 96500 C is called the Faraday constant. Faraday (96500 C) is the charge of 1 mole electron, i.e., `6.023 xx 10^(23)` electrons, it is used to liberate one gram equivalent of the substance.
Calculate the volume of gas liberated at the anode at STP during the electrolysis of a `CuSO_(4)` solution by a current of 1 A passed for 16 minutes and 5 seconds :

A

224 mL

B

56 mL

C

112 mL

D

448 mL

Text Solution

Verified by Experts

The correct Answer is:
B

At anode: `2OH^(-) rarr H_(2)O+1/2 O_(2) +2e^(-)`
(Oxygen gas is evolved)
Equivalent volume `V_(e)` of oxygen =5.6 litre
`:. V=(ItV_(e))/96500=(1xx965xx5.6xx10^(3))/96500=56 mL`
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Electrolysis is the process in which electrical energy is converted to chemical energy. In electrolytic cell, oxidation takes place at anode and reduction at cathode. Electrode process depends on the electrode taken for electrolysis. Amount of substance liberated at an electrode is directly propertional to the amount of charge passed through it. The mass of substance liberated at electrode is calculated using the following relation : m= ("ItE")/(96500) Here, E represents the equivalent mass and 96500 C is called the Faraday constant. Faraday (96500 C) is the charge of 1 mole electron, i.e., 6.023 xx 10^(23) electrons, it is used to liberate one gram equivalent of the substance. On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be :

Electrolysis is the process in which electrical energy is converted to chemical energy. In electrolytic cell, oxidation takes place at anode and reduction at cathode. Electrode process depends on the electrode taken for electrolysis. Amount of substance liberated at an electrode is directly propertional to the amount of charge passed through it. The mass of substance liberated at electrode is calculated using the following relation : m= ("ItE")/(96500) Here, E represents the equivalent mass and 96500 C is called the Faraday constant. Faraday (96500 C) is the charge of 1 mole electron, i.e., 6.023 xx 10^(23) electrons, it is used to liberate one gram equivalent of the substance. The platinum electrodes were immersed in a solution of cupric sulphate (CuSO_(4)) and electric current is passed through the solution. after sometime, it was observed that the colour of copper sulphate disappeared with evolution of a gas at the electrode. The colourless solution contains :

Knowledge Check

  • Electrolysis is the process in which electrical energy is converted to chemical energy. In electrolytic cell, oxidation takes place at anode and reduction at cathode. Electrode process depends on the electrode taken for electrolysis. Amount of substance liberated at an electrode is directly propertional to the amount of charge passed through it. The mass of substance liberated at electrode is calculated using the following relation : m= ("ItE")/(96500) Here, E represents the equivalent mass and 96500 C is called the Faraday constant. Faraday (96500 C) is the charge of 1 mole electron, i.e., 6.023 xx 10^(23) electrons, it is used to liberate one gram equivalent of the substance. The passage of current liberates H_(2) at cathode and Cl_(2) at anode. The solution is :

    A
    copper chloride in water
    B
    NaCl in water
    C
    mercuric chloride in water
    D
    `AuCl_(3)` in water
  • Electrolysis is the process in which electrical energy is converted to chemical energy. In electrolytic cell, oxidation takes place at anode and reduction at cathode. Electrode process depends on the electrode taken for electrolysis. Amount of substance liberated at an electrode is directly propertional to the amount of charge passed through it. The mass of substance liberated at electrode is calculated using the following relation : m= ("ItE")/(96500) Here, E represents the equivalent mass and 96500 C is called the Faraday constant. Faraday (96500 C) is the charge of 1 mole electron, i.e., 6.023 xx 10^(23) electrons, it is used to liberate one gram equivalent of the substance. How many faradays are required to reduce 1 mol BrO_(3)^(-) to Br^(-) ?

    A
    3
    B
    5
    C
    6
    D
    4
  • Electrolysis is the process in which electrical energy is converted to chemical energy. In electrolytic cell, oxidation takes place at anode and reduction at cathode. Electrode process depends on the electrode taken for electrolysis. Amount of substance liberated at an electrode is directly propertional to the amount of charge passed through it. The mass of substance liberated at electrode is calculated using the following relation : m= ("ItE")/(96500) Here, E represents the equivalent mass and 96500 C is called the Faraday constant. Faraday (96500 C) is the charge of 1 mole electron, i.e., 6.023 xx 10^(23) electrons, it is used to liberate one gram equivalent of the substance. The quantity of electricity required to liberate 112 cc hydrogen at S.T.P. from acidified water is :

    A
    965 C
    B
    9650 C
    C
    96500 C
    D
    4825 C
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