Home
Class 12
CHEMISTRY
Explain why aldehydes are more reactios ...

Explain why aldehydes are more reactios than ketones.

Text Solution

Verified by Experts

The carbonyl group is polar in nature

Lower positive charge on the carbon of carbonuyl group makes the aldehyde or keto less reactive towards nucleophilies. In ketones, the positive charge on the carbonly carbon is lowred by high + I effect of tw alkyl grougps in comparison to aldehyde in which one alkyl group is present. Further increases in the number of alkyl groups also increases eh steric hindrance making it less recative. Thus, in generalk, aldehydes are more reactive than ketones.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ALDEHYDES AND KETONES

    OP TANDON|Exercise ILLUSTRATIONS OF OBJECTIVE QUESTIONS|12 Videos
  • ALDEHYDES AND KETONES

    OP TANDON|Exercise PROBLEMS FOR PRACTICE|14 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    OP TANDON|Exercise SINGLE INETER ANSWER TYPE QUESTIONS / ALCOHOLS AND PHENOLS|15 Videos
  • BASIC PRINCIPLES

    OP TANDON|Exercise SECTION V INTEGER ANSWER TYPE QUESTION|3 Videos