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In an acidified solution of K2Cr2O7, H2O...

In an acidified solution of `K_2Cr_2O_7, H_2O_2` is added. Then

A

solution turns green due to formation of `Cr_2O_3`

B

solution turns yellow due to formation of `K_2CrO_4`

C

a blue coloured compound `CrO(O_2)_(2)` is formed

D

solution gives green precipitate of `Cr(OH)_(3)`

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The correct Answer is:
To solve the question regarding the reaction that occurs when hydrogen peroxide (H2O2) is added to an acidified solution of potassium dichromate (K2Cr2O7), we can follow these steps: ### Step 1: Identify the Reactants In this reaction, the reactants are potassium dichromate (K2Cr2O7) and hydrogen peroxide (H2O2) in an acidified solution. ### Step 2: Understand the Reaction Conditions The solution is acidified, which means that an acid (like sulfuric acid, H2SO4) is present. This acidic environment is crucial for the reaction to proceed correctly. ### Step 3: Determine the Products When H2O2 is added to an acidified solution of K2Cr2O7, a redox reaction occurs. The chromium in K2Cr2O7 is in the +6 oxidation state and gets reduced, while H2O2 acts as a reducing agent. ### Step 4: Write the Balanced Chemical Equation The balanced chemical equation for the reaction is: \[ K_2Cr_2O_7 + H_2O_2 + H_2SO_4 \rightarrow CrO_2 \cdot H_2O + K_2SO_4 + H_2O \] In this reaction, the chromium is reduced to a lower oxidation state, forming a deep blue compound known as chromium diperoxide (CrO2). ### Step 5: Identify the Color Change The formation of chromium diperoxide (CrO2) results in a deep blue color in the solution. This is a significant indicator of the reaction taking place. ### Conclusion Based on the above steps, the correct answer to the question is that the solution turns blue due to the formation of CrO2, which corresponds to option C.
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