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In an acidified solution of K2Cr2O7, H2O...

In an acidified solution of `K_2Cr_2O_7, H_2O_2` is added. Then

A

solution turns green due to formation of `Cr_2O_3`

B

solution turns yellow due to formation of `K_2CrO_4`

C

a blue coloured compound `CrO(O_2)_(2)` is formed

D

solution gives green precipitate of `Cr(OH)_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction that occurs when hydrogen peroxide (H2O2) is added to an acidified solution of potassium dichromate (K2Cr2O7), we can follow these steps: ### Step 1: Identify the Reactants In this reaction, the reactants are potassium dichromate (K2Cr2O7) and hydrogen peroxide (H2O2) in an acidified solution. ### Step 2: Understand the Reaction Conditions The solution is acidified, which means that an acid (like sulfuric acid, H2SO4) is present. This acidic environment is crucial for the reaction to proceed correctly. ### Step 3: Determine the Products When H2O2 is added to an acidified solution of K2Cr2O7, a redox reaction occurs. The chromium in K2Cr2O7 is in the +6 oxidation state and gets reduced, while H2O2 acts as a reducing agent. ### Step 4: Write the Balanced Chemical Equation The balanced chemical equation for the reaction is: \[ K_2Cr_2O_7 + H_2O_2 + H_2SO_4 \rightarrow CrO_2 \cdot H_2O + K_2SO_4 + H_2O \] In this reaction, the chromium is reduced to a lower oxidation state, forming a deep blue compound known as chromium diperoxide (CrO2). ### Step 5: Identify the Color Change The formation of chromium diperoxide (CrO2) results in a deep blue color in the solution. This is a significant indicator of the reaction taking place. ### Conclusion Based on the above steps, the correct answer to the question is that the solution turns blue due to the formation of CrO2, which corresponds to option C.
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When SO_2 gas is passed through an acidified solution of K_2 Cr_2 O_7 , the solution turns ___ in colour.

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Knowledge Check

  • When acidified solution of K_(2)Cr_(2)O_(7) is shaken with aqeous solution of FeSO_(4) , Then:

    A
    `Cr_(2)O_(7)^(2-) ` ions is reduced to `Cr^(3+)` ions
    B
    `Cr_(2)O_(7)^(2-)` ion is converted to `CrO_(4)^(2-)` ion
    C
    `Cr_(2)O_(7)^(2-)` ions is reduced to `Cr`
    D
    `Cr_(2)O_(7)^(2-)` ions is converted to `CrO_(3)`
  • When H_(2)O_(2) is shaken with an acidified solution of K_(2)Cr_(2)O_(7) in the presence of ether , the ethereal layer turns blue due to the formation of

    A
    `Cr_(2)O_(3)`
    B
    `CrO_(4)^(-)`
    C
    `Cr_(2)(SO_(3))_(3)`
    D
    `CrO_(5)`
  • When H_(2)O_(2) is shaken with an acidified solution of K_(2)Cr_(2)O_(7) in presence of ether, the ethereal layer turns blue due to the formation of

    A
    `Cr_(2)O_(3)`
    B
    `CrO_(4)^(2-)`
    C
    `Cr_(2)(SO_(4))_(3)`
    D
    `CrO_(3)`
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