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In the given reaction, CH(3)-underset(...

In the given reaction,
`CH_(3)-underset(CH_3)underset(|)(CH)-overset(O)overset(||)(C )-CH_2-CH_3 overset(CF_3CO_3H)(rarr)(X)`
as main product, 'X' will be

A

`CH_3-CH_2-overset(O)overset(||)(C )-O-underset(CH_3)underset(|)(CH)-CH_3`

B

`CH_3-underset(CH_3)underset(|)(CH)-overset(O)overset(||)(C )-O-CH_2-CH_3`

C

`CH_3-C-overset(O)overset(||)(C )-OC(CH_3)_(3)`

D

`(CH_3)_(2)COOCH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction of the given compound with peracetic acid (CF3CO3H) and determine the product 'X' formed in the reaction. ### Step-by-Step Solution: 1. **Identify the Reactant**: The reactant is a ketone, which has the structure: \[ CH_3 - C(=O) - CH_2 - CH_3 \] Here, the carbonyl carbon is bonded to two alkyl groups (one methyl and one ethyl). 2. **Understand the Reaction**: The reaction involves peracetic acid, which is a peracid. When a ketone reacts with a peracid, it undergoes a reaction known as the Bayer-Villiger oxidation. 3. **Bayer-Villiger Reaction**: In the Bayer-Villiger reaction, the ketone is converted into an ester. The oxygen from the peracid is inserted between the carbonyl carbon and one of the alkyl groups attached to it. 4. **Determine Migratory Aptitude**: The migratory aptitude determines which alkyl group will be replaced by the oxygen. In this case, we have: - R1 (methyl group, CH3) - R2 (ethyl group, CH2-CH3) According to migratory aptitude, the order is: - Tertiary > Secondary > Primary > Hydrogen > Phenyl In our case, the ethyl group (R2) is secondary and the methyl group (R1) is primary. Therefore, the secondary group (ethyl) has a higher migratory aptitude than the primary group (methyl). 5. **Product Formation**: Since the ethyl group has a higher migratory aptitude, the oxygen from the peracid will migrate to the position adjacent to the ethyl group. This results in the formation of the ester: \[ CH_3 - O - C(=O) - CH_2 - CH_3 \] This structure corresponds to ethyl acetate. 6. **Final Product 'X'**: The final product 'X' formed from the reaction of the ketone with peracetic acid is: \[ CH_3 - O - C(=O) - CH_2 - CH_3 \] Which is ethyl acetate. ### Conclusion: The main product 'X' will be an ester, specifically ethyl acetate.
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