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Mention the conditions for combination o...

Mention the conditions for combination of atomic orbitals.

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The conditions for the combination of atomic orbitals are
1) The combining atomic orbitals should have comparable energy. 1s orbital can combine with another 1 s orbital but not with 2s orbital. 2) The combining atomic orbitals should have the same symmetry about the moecular axis. For example : 2p orbital can combine with 2s orbital or another `2p_(z)` orbital but not with `2p_(x)or2p_(y)`.
2s cannot combine with `2p_(x)or2p_(y)`
3) The combining atomic orbitals must overlap to the maximum extent.
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Knowledge Check

  • Which of the following combinations of atomic orbitals gives antibonding pi MO (assume z - axis as internuclear axis) ?

    A
    1. `2s+2p_(z)`
    B
    2. `2p_(y)+2p_(y)`
    C
    3. `2p_(x)-2p_(x)`
    D
    4. `2p_(z)-2p_(z)`
  • The orientation of an atomic orbital is governed by

    A
    spin quantum number
    B
    magnetic quantum number
    C
    principal quantum number
    D
    Azimuthal quantum number
  • d^2sp^3 hybridisation of atomic orbitals gives

    A
    square planar structure
    B
    octahedral structure
    C
    tetragonal structure
    D
    triangular structure
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