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Write the rules for assigning oxidation ...

Write the rules for assigning oxidation number.

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(1) All atoms in the elemental or molecules state have zero oxidation state.
(2) Elements of group I and II in the periodic table always have +1 and +2 oxidation states respectively
(3) Hydrogen has +1 oxidation state in all its compounds except metal hydrides, where it is -1.
(4) Oxygen has been assigned as oxidation number of -2 in all its compounds except perocides and oxygen fluoride. In peroxide it is -1 and in oxygen fluoride it is +2.
(5) Halogens generally have -1 oxidation state Except fluorine. other halogens may have positive oxidation states in their oxides and inter halogen compounds (Fluorine always has -1 state).
(6) The algebraic sum of the oxidation number of all the elements in a compound is zero and that in an ion is equal to the net charge on the ion.
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Knowledge Check

  • Select the compound in which chlorine is assigned the oxidation number +7.

    A
    `HClO_4`
    B
    `HClO_2`
    C
    `HClO_3`
    D
    HCl
  • In which of the following oxidation number of carbon is-1

    A
    `CH_4`
    B
    `C_6H_6`
    C
    `CCl_4`
    D
    HCHO
  • In which of the following oxidation number of Mn is not +7

    A
    `K_2MnO_4`
    B
    `Mn_2O_7`
    C
    `MnO_4^-`
    D
    `KMnO_4`
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