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The hydrolysis of ethyl acetate CH(3)COO...

The hydrolysis of ethyl acetate `CH_(3)COOC_(2)H_(5) + H_(2)O overset(H^(+))to CH_(3)COOH + C_(2)H_(5)OH` is a reaction of

A

Pseudo first order

B

Second order

C

Third order

D

Zero order

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To determine the order of the hydrolysis of ethyl acetate, we can follow these steps: ### Step 1: Write the Reaction The hydrolysis of ethyl acetate can be represented as: \[ \text{CH}_3\text{COOC}_2\text{H}_5 + \text{H}_2\text{O} \overset{H^+}{\rightarrow} \text{CH}_3\text{COOH} + \text{C}_2\text{H}_5\text{OH} \] ### Step 2: Identify the Reactants In this reaction, the reactants are: 1. Ethyl acetate (\( \text{CH}_3\text{COOC}_2\text{H}_5 \)) 2. Water (\( \text{H}_2\text{O} \)) ### Step 3: Consider the Concentration of Water In hydrolysis reactions, water is often used in excess. This means that its concentration remains relatively constant throughout the reaction. Therefore, we can treat the concentration of water as a constant. ### Step 4: Write the Rate Law Expression The general rate law expression for a reaction involving two reactants is: \[ \text{Rate} = k[\text{A}][\text{B}] \] Where \( \text{A} \) and \( \text{B} \) are the reactants. However, since water is in excess, we can simplify the expression: \[ \text{Rate} = k'[\text{CH}_3\text{COOC}_2\text{H}_5] \] Where \( k' = k[\text{H}_2\text{O}] \) (since \([\text{H}_2\text{O}]\) is constant). ### Step 5: Determine the Order of the Reaction From the rate law expression, we see that the rate depends only on the concentration of ethyl acetate. This indicates that the reaction behaves as a first-order reaction with respect to ethyl acetate. ### Step 6: Conclusion Since the reaction is first-order with respect to ethyl acetate and the concentration of water does not affect the rate, we classify this reaction as a **pseudo first-order reaction**. Therefore, the order of hydrolysis of ethyl acetate is **pseudo first order**. ### Final Answer The hydrolysis of ethyl acetate is a pseudo first-order reaction. ---

To determine the order of the hydrolysis of ethyl acetate, we can follow these steps: ### Step 1: Write the Reaction The hydrolysis of ethyl acetate can be represented as: \[ \text{CH}_3\text{COOC}_2\text{H}_5 + \text{H}_2\text{O} \overset{H^+}{\rightarrow} \text{CH}_3\text{COOH} + \text{C}_2\text{H}_5\text{OH} \] ### Step 2: Identify the Reactants In this reaction, the reactants are: ...
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The hydrolysis of ethyl acetat CH_3COOC_2H_5+H_2O overset(H^(+))to CH_3COOH + C_2H_5OH is a reaction of

The hydrolysis of ethyl acetate CH_(3)COOC_(2)H_(3)+H_(2)O hArr CH_(3) COOH + C_(2)H_(5)OH in aqueous solution is first order with respect to ethyl acetate. Upon varying the pH of the solution the first order rate constant varies as follows. pH" "3" "2" "1 k_(1)xx10^(-4)s^(-1)" "1.1" "11" "110 what is the order of the reaction with respect of H^(+) and the value of the rate constant ?

Knowledge Check

  • The hydrolysis of ethyl acetate is a reaction of : CH_3COOC_2H_5 + H_2O overset(H^(+))to CH_3COOH + C_2H_5OH

    A
    First order
    B
    Second order
    C
    Third order
    D
    Zero order
  • The reaction CH_(3)COOC_(2)H_(5)+H_(2)O+H_(2)O overset(H^(+))to CH_(3)COOH+C_(2)H_(5)OH is of

    A
    first order.
    B
    pseudo first order.
    C
    zero order.
    D
    second order.
  • The hydrolysis of ethyl acetate is a reaction of : CH_(3)COOC_(2)H_(5)+H_(2)Ooverset(H^(+))rarr CH_(3)COOH+C_(2)H_(5)OH

    A
    zero order
    B
    first order
    C
    second order
    D
    third order
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