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For the elem entary reaction 2A to C the...

For the elem entary reaction `2A to C` the concentration of A after 30 minutes was found to be 0.01 mole/lit. If the rate constant of the reaction is `2.5 xx 10^(-2)` lit `"mole"^(-1)sec^(-1)` the rate of the reaction at 30 minutes is

A

`2.5 xx 10^(-4)"mole"^(-1)"lit"^(-1)sec^(-1)`

B

`2.5 xx 10^(-6)"mole lit"^(-1)"sec"^(-1)`

C

`2.5 xx 10^(-2) "mole lit"^(-1)"sec"^(-1)`

D

`2.5 xx 10^(-8) "mole"^(-1)"lit"^(1)"sec"^(-1)`

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The correct Answer is:
To solve the problem step by step, we need to determine the rate of the reaction at 30 minutes given the concentration of A and the rate constant. ### Step 1: Understand the Reaction The reaction given is: \[ 2A \rightarrow C \] This indicates that two moles of A are consumed to produce one mole of C. ### Step 2: Identify Given Data From the problem, we have: - Concentration of A after 30 minutes, \([A] = 0.01 \, \text{mol/L}\) - Rate constant, \(k = 2.5 \times 10^{-2} \, \text{L mol}^{-1} \text{s}^{-1}\) ### Step 3: Write the Rate Law For an elementary reaction of the form \(2A \rightarrow C\), the rate law can be expressed as: \[ \text{Rate} = k [A]^n \] Since the reaction is elementary and the stoichiometry indicates that two moles of A are involved, we have: \[ n = 2 \] Thus, the rate law becomes: \[ \text{Rate} = k [A]^2 \] ### Step 4: Substitute the Values Now, we can substitute the values of \(k\) and \([A]\) into the rate equation: \[ \text{Rate} = (2.5 \times 10^{-2} \, \text{L mol}^{-1} \text{s}^{-1}) \times (0.01 \, \text{mol/L})^2 \] ### Step 5: Calculate the Rate Calculating \((0.01 \, \text{mol/L})^2\): \[ (0.01)^2 = 0.0001 \, \text{mol}^2/\text{L}^2 \] Now substituting back into the rate equation: \[ \text{Rate} = (2.5 \times 10^{-2}) \times (0.0001) \] \[ \text{Rate} = 2.5 \times 10^{-6} \, \text{mol L}^{-1} \text{s}^{-1} \] ### Step 6: Final Answer Thus, the rate of the reaction at 30 minutes is: \[ \text{Rate} = 2.5 \times 10^{-6} \, \text{mol L}^{-1} \text{s}^{-1} \]

To solve the problem step by step, we need to determine the rate of the reaction at 30 minutes given the concentration of A and the rate constant. ### Step 1: Understand the Reaction The reaction given is: \[ 2A \rightarrow C \] This indicates that two moles of A are consumed to produce one mole of C. ### Step 2: Identify Given Data ...
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NARAYNA-CHEMICAL KINETICS -EXERCISE -2 (C.W) RATE OF REACTION & FACTORS
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  7. The concentration of reaction decreases from 0.2 M to 0.05 M in 5 minu...

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  8. A rarr B, k(A)=10^(15) e^(-2000//T) C rarr D, k(c)=10^(14) e^(-1000/...

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  11. Consider a system containing NO(2) and SO(2) in which NO(2) is consum...

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  12. Consider a reaction, 2A + B rarr Products When concentration of B al...

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  13. For a reaction, the rate constant is expressed as k = Ae^(-40000//T). ...

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  14. The reaction CH(3)COOC(2)H(5) + NaOH to CH(3)COONa + C(2)H(5)OH is a...

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  15. For the decomposition reaction: N(2)O(4(g))rarr 2NO(2(g)), the initi...

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  16. The rate for the decomposition of NH(3) on platinum surface is zero or...

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  17. "1 dm"^(3) of 2 M CH(3)COOH is mixed with "1 dm"^(3) of 3 M ethanol to...

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  18. For a reaction, K = 2 xx 10^(13) e^(-30000//RT). When log K(y-axis) is...

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  20. Give the following data for the reaction: X + Y to Z Which one ...

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