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Aldehydes are isomeric with...

Aldehydes are isomeric with

A

ketones

B

Ethers

C

Alcohols

D

Fatty acids

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The correct Answer is:
To determine which compounds are isomeric with aldehydes, we need to understand the definition of isomerism and the structure of aldehydes. ### Step-by-Step Solution: 1. **Understanding Aldehydes**: - Aldehydes have the general formula \( RCHO \), where \( R \) is a hydrocarbon group. The carbonyl group (C=O) is at the end of the carbon chain. 2. **Identifying Isomeric Compounds**: - Isomeric compounds must have the same molecular formula but different structural formulas. This means they can have different functional groups or arrangements of atoms. 3. **Analyzing the Options**: - **Option A: Ketones**: - Ketones have the general formula \( RC(=O)R' \). For example, the simplest ketone is acetone, \( CH_3COCH_3 \). - An aldehyde with three carbons is \( CH_3CH_2CHO \) (propionaldehyde). Both have the same molecular formula \( C_3H_6O \), hence they are isomers. - **Option B: Ethers**: - Ethers have the general formula \( ROR' \). For example, dimethyl ether is \( CH_3OCH_3 \). - An aldehyde with two carbons is \( CH_3CHO \) (acetaldehyde). The molecular formula for dimethyl ether is \( C_2H_6O \), which is different from \( C_2H_4O \) (the formula for acetaldehyde). Thus, they are not isomers. - **Option C: Alcohols**: - Alcohols have the general formula \( ROH \). For example, ethanol is \( CH_3CH_2OH \). - An aldehyde with two carbons is \( CH_3CHO \). The molecular formula for ethanol is \( C_2H_6O \), which differs from \( C_2H_4O \). Therefore, they are not isomers. - **Option D: Carboxylic Acids**: - Carboxylic acids have the general formula \( RCOOH \). For example, acetic acid is \( CH_3COOH \). - An aldehyde with two carbons is \( CH_3CHO \). The molecular formula for acetic acid is \( C_2H_4O_2 \), which is different from \( C_2H_4O \). Hence, they are not isomers. 4. **Conclusion**: - The only option that is isomeric with aldehydes is **Option A: Ketones**.

To determine which compounds are isomeric with aldehydes, we need to understand the definition of isomerism and the structure of aldehydes. ### Step-by-Step Solution: 1. **Understanding Aldehydes**: - Aldehydes have the general formula \( RCHO \), where \( R \) is a hydrocarbon group. The carbonyl group (C=O) is at the end of the carbon chain. 2. **Identifying Isomeric Compounds**: ...
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Knowledge Check

  • Aldehydes act as

    A
    oxidizing agents
    B
    reducing agents
    C
    dehydrating agents
    D
    neutral agents
  • Aldehydes act as

    A
    catalyst
    B
    oxidizing agent
    C
    mordant
    D
    reducing agent
  • Aldehydes and ketones

    A
    are insoluble in organic solvents like benzene, ether, methanal, chloroform etc.
    B
    solubility increases rapidly on increasing the length of the alkyl chain
    C
    are used in the blending of perfumes and flavouring agents
    D
    all of the above.
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    A : Aromatic aldehydes are less reactive than aliphatic aldehyde towards nucleophilic substitution reaction. R : In case of aromatic aldehyde,+R effect of phenyl ring is present.