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To convert glucose to saccharic acid the...

To convert glucose to saccharic acid the reagent used is

A

bromine water

B

Fehling's solution

C

Nitric acid

D

Alkaline solution of Iodine

Text Solution

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The correct Answer is:
To convert glucose to saccharic acid, the reagent used is nitric acid. Here’s a step-by-step explanation of the process: ### Step 1: Understand the Structures - **Glucose Structure**: Glucose is a six-carbon sugar (hexose) with the molecular formula C₆H₁₂O₆. It contains an aldehyde group (-CHO) at one end and multiple hydroxyl groups (-OH) attached to its carbon skeleton. - **Saccharic Acid Structure**: Saccharic acid (also known as glucaric acid) is a dicarboxylic acid derived from glucose, where both the aldehyde group and the primary alcohol group are oxidized to carboxylic acid groups (-COOH). ### Step 2: Identify the Reagents - **Mild Oxidizing Agents**: Reagents like bromine water and Fehling's solution can oxidize the aldehyde group of glucose to form gluconic acid but will not oxidize the alcohol group. - **Strong Oxidizing Agents**: Nitric acid is a strong oxidizing agent that can oxidize both the aldehyde group and the primary alcohol group of glucose to carboxylic acids. ### Step 3: Reaction with Nitric Acid - When glucose reacts with nitric acid, both the aldehyde group and the primary alcohol group are oxidized. - The reaction can be represented as: - Glucose (C₆H₁₂O₆) + HNO₃ → Saccharic Acid (C₆H₈O₆) + other products. ### Step 4: Conclusion - The reagent used to convert glucose to saccharic acid is **nitric acid**. ### Summary - **Glucose** is oxidized by **nitric acid** to form **saccharic acid**.
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