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State as to why (a) Alkali metals sho...

State as to why
(a) Alkali metals show only +1 oxidation state
(b) Na and K impart colour to the flame but Mg does not.lt
(c) Lithium on being heated in air mainly forms the monoxide and not the peroxide
(d) Li is the best reducing agent in aqueous solution

Text Solution

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Alkali metals have low jonization enthalpies
They have a strong tendency to lose 1 electron to form unipositive ions. Thus they show an oxidation state of +1 and are strongly electropositive.
(b) Valence electrons of alkali metals like Na and K easily absorb energy from the flame and are excited to higher energy levels. When these electrons return to the ground state, the energy is emitted in the form of light. Magnesium atom has small size so electrons are strongly bound to the nucleus. Thus they need large amount of energy for excitation of electrons to higher energy levels, which is not possible in Bunsen flame.
(c) Due to the small size of `Li^(+)` it has a strong positive field, which attracts the negative charge so strongly that it does not permit the oxide ion `(O^(2-))` to combine with another oxygen atom to form peroxide ion.
(d) Among alkali metals, lithium has the most negative electrode potential`(Etheta -3.04 V)`, so it is the strongest reducing agent in the aqueous solution
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Figure shows a metal rod PQ resting on the smooth rails AB and positioned between the poles of a permanent magnet. The rails, the rod and the magnetic field are in three mutually perpendicular directions. A galvonometer G connects the rails through a switch K. Length of rod = 15 cm, B = 0.50 T, resistance of the closed loop containing the rod = 9.0mOmega . Assume the field to be uniform. a. Suppose K is open and the rod is moved with a speed of 12cms^(-1) in the direction shown. Give the polarity and magnitude of the induced emf. b. Is there an excess charge built up at the ends of the rods when K is open? What if K is closed? c. With K open and the rod moving uniformly, there is no net force on the electrons in the rod PQ eventhough they do experience magnetic force due to the motion of the rod. Explain. d. What is the retarding force on the rod when K is closed? e. How much power is required (by an external agent) to keep the rod moving at the same speed (=12cms^(-1)) when K is closed? How much power is required when K is open? f. How much power is dissipated as heat in the closed circuit? What is the source of this power? g. What is the induced emf in the moving rod if the magnetic field is parallel to the rails instead of being perpendicular?

FULL MARKS-ALKALI AND ALKALINE EARTH METALS-Additional Questions Solved
  1. List out the uses of magnesium

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  2. Distinguish between alkali metals and alkaline earth metals.

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  3. State as to why (a) Alkali metals show only +1 oxidation state ...

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  4. An alkali metal (A) belongs to period number II and group number I rea...

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  5. Describe solvay process (or) how is washing soda ( or) sodium carbonat...

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  6. How is sodium hydroxide prepared commercially from brine solution?

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  7. Why alkali metals and alkaline earth metals are called s-block element...

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  8. Why group 1 elements are called alkali metals?

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  9. Which is the radioactive element in group 1 element? What is its half-...

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  10. Alkali metals are stored under oil. Give reason.

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  11. Name the list of elements present in alkali metal group. What is the c...

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  12. Alkali metals never found in free state in nature. Why?

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  13. The second ionization enthalpy of alkali metals are very high. Give re...

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  14. LICIO(4) is more soluble than NaCIO(4)Why?

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  15. Why does lithium exhibit anomalous properties ?

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  16. Why alkali metals have high chemical reactivity? How this changes alon...

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  17. Lithium forms monoxide with oxygen whereas sodium forms peroxide with ...

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  18. Explain the action of hydrogen with alkali metals

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  19. Alkali metal hydrides are strong reducing agents. Prove this statement...

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  20. Explain the action of halogen with alkali metals

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