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Prove that the depression in freezing po...

Prove that the depression in freezing point is a colligative property.

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(i) The electrolyte NaCl dissociates completely into its constituent ions in their aqueous solution. This causes an increase in the total number of particles present in the solution.
(ii) When we dissolve 1 mole of NaCl in water. It, dissociates and gives 1 mole of `Na^(+)` and 1 mole of `Cl ^(-).` Hence the solution will have 2 moles of particles. But when we dissolve 1 mole of urea (non electrolyte) in water it appears as 1 mole only. So the colligative property value would be double in NaCl than in urea.
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Knowledge Check

  • Assertion: When sodium chloride is added to water, a depression in freezing point is observed . Reason : The lowering of vapour pressure of a solution, causes the depression in freezing point

    A
    Both assertion and reason are true and reason is the correct explanation of assertion.
    B
    Both assertion and reason are true but reason is not the correct explanation for assertion.
    C
    Assertion is true but reason is false.
    D
    Both assertion and reason are false.
  • Assertion : When NaCl is added to water, a depression in freezing point is observed. Reason: The lowering of vapour pressure of a solution causes the depression in freezing point.

    A
    Assertion and Reason are correct and R is the correct explanation of A.
    B
    Both A and R are correct R is not the correct explanation of A.
    C
    A is correct but R is wrong
    D
    A is wrong but R is correct
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