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Explain Aluminothermic process....

Explain Aluminothermic process.

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Metallic oxides such as `Cr_(2)O_(3)` can be reduced by an aluminothermic process. In this process, the metal oxide is mixed with aluminium powder and placed in a fire clay crucible. To initiate the reduction process, an ignition mixture (usually magnesium and barium peroxide) is used.
`"BaO"_(2)+Mg to"BaO"+"MgO"`
During the above reaction a large amount of heat is evolved (temperature upto `2400^(@)C`, is generated and the reaction enthalpy is : `852" kJ mol"^(-1)`) which facilitates the reduction of `Cr_(2)O_(3)` by aluminium power.
`"Cr"_(2)"O"_(3)+2Al overset(Delta)to2Cr+Al_(2)O_(3)`
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Knowledge Check

  • Assertion : Aluminothermic process is the extraction of chromium from chromic oxide. Reason : Alumina has a high melting point.

    A
    Both (A) and (R ) are true and (R ) is the correct explanation of (A).
    B
    Both (A) and (R ) are true and (R ) is not the correct explanation of (A).
    C
    (A) true but (R ) false.
    D
    Both (A) and (R ) are false.
  • In the aluminothermic process

    A
    `Al_2O_3 " is reduced by " Cr`
    B
    `Cr_2O_3 " is reduced by " Al`
    C
    `Al_2O_3 " is reduced by " C`
    D
    None of these corrcet
  • Ignition mixture used in aluminothermic process is ………….

    A
    `Mg + BaO_2`
    B
    `MgO + BaO`
    C
    `Al_2O_3 + Mg`
    D
    `Al_2O_3 + BaO_2`
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