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Using crystal field theory, explain the ...

Using crystal field theory, explain the colour of the coordination compound.

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`(i)` The ligand field causes the splitting of d orbitals of the central metal atom into two sets (`t_(2g)` and eg).
`(ii)` When the white light falls on the complex ion, the central metal ion absorbs visible light corresponding to the crystal field splitting energy and transmits rest of the light which is responsible for the colour of the complex.
`(iii)` This absorption causes excitation of d-electrons of the central metal ion from the lower energy `t_(2g)` level to the higher energy eg level which is known as d-d transition.
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FULL MARKS-COORDINATION CHEMISTRY-Additional Question(3 Marks Question)
  1. Explain Werner's postulate using COCl(3).6NH(3).

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  2. What is the oxidation state in coordination compound ?

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  3. Explain the types of complexes based on the charge on the complex.

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  4. What is meant by ligand ? Explain their types with examples.

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  5. Identify the following terms in the complex K(4)[Fe(CN)(6)] (i) Cati...

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  6. Identify and write the following in the complex [CO(NH(3))(4)Cl(2)]Cl ...

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  7. Write the following in the complex [Cr(en)(3)][CrF(6)] (i) Types of ...

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  8. Write the IUPAC names of the following complexes (i) [Co(NH(3))(5)CN...

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  9. Explain coordination isomerism with suitable example.

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  10. Explain ionisation isomerism with suitable example.

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  11. Explain the type of isomers possible for the formula [Cr(H(2)O(6)]Cl(3...

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  12. Mention the coordination number, hybridisation and geometry of the fol...

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  13. Mention the coordination number, hybridisation and geometry of the fol...

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  14. How is spectrochemical series is used to identify the type of ligands ...

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  15. Most of the transition metal complexes are coloured . Justify this sta...

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  16. Using crystal field theory, explain the colour of the coordination com...

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  17. [Ti(H(2)O)(6)]^(2+) is purple in colour. Prove this statement

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  18. Cu^(+), Zn^(2+), Sc^(3+), Ti^(4+) are colourless. Prove this statement...

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  19. Explain about the bonding in metal carbonyls.

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  20. Explain the medicinal application of coordination compounds ?

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