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Using crystal field theory, explain the ...

Using crystal field theory, explain the colour of the coordination compound.

Text Solution

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`(i)` The ligand field causes the splitting of d orbitals of the central metal atom into two sets (`t_(2g)` and eg).
`(ii)` When the white light falls on the complex ion, the central metal ion absorbs visible light corresponding to the crystal field splitting energy and transmits rest of the light which is responsible for the colour of the complex.
`(iii)` This absorption causes excitation of d-electrons of the central metal ion from the lower energy `t_(2g)` level to the higher energy eg level which is known as d-d transition.
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Knowledge Check

  • Kinetic theory explains the behavior

    A
    of solids and liquid Based on the idea that the gas consists of rapidly vibrating atoms or molecules
    B
    of gases based on the idea that the gas consists of rapidly moving atoms or molecules
    C
    of solids based on the idea that the solid consists of rapidly vibrating atoms or molecules
    D
    of liquid based on the idea that the liquid consist of rapidly moving atoms or molecules
  • Consider the following statements (i) VB theory does not explain the colour of the complex (ii) VB theory does not explain the magneitc properties (iii) Vb theory does not provide a quantative explanation about inner orbital complexes. Which of the above statements is/are not correct ?

    A
    `i` only
    B
    `i` and `ii`
    C
    `iii` only
    D
    `ii` only
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