Home
Class 12
CHEMISTRY
According to Bayer's strain theory which...

According to Bayer's strain theory which is highly stable?

A

Cyclobutane

B

Cyclopentane

C

Cycloheptane

D

Cyclohexane

Text Solution

Verified by Experts

The correct Answer is:
C

Bayer's strain theory - The amount of strain is directly proportional to the angle through which a valency bond has deviated from its normal position i.e. Amount of deviation (d).
`d = (1)/(2)(109^(@)28'` - valency angle)
In cyclobutane , `d = (1)/(2) (109^(@)28' - 90^(@)) = 9^(@)44'`
In cyclopentane , `d = (1)/(2) (109^(@)28' - 108^(@)) = 0^(@)44'`
In cyclohexane, `d = (1)/(2) (109^(@)28' - 120^(@)) = -5^(@)16'`
In cycloheptane , `d = (1)/(2) (109^(@)28' - 135^(@)) = -9^(@)33'`
Cyclopentane is more stable and less reactive compared to cyclobutane, and cyclohexane and cycloheptane are free from angle of strain.Therefore quite stable.But actually Bayer's theory fails for the rings containing six or more carbone atoms.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • KARNATAKA CET 2006

    KCET PREVIOUS YEAR PAPERS|Exercise CHEMISTRY|60 Videos
  • KARNATAKA CET 2008

    KCET PREVIOUS YEAR PAPERS|Exercise CHEMISTRY|60 Videos

Similar Questions

Explore conceptually related problems

According to the Neo-Darwinian theory, which of the following is responsible for the origin of new species

According to molecular orbital theory, which of the following will not be a viable molecule?

Knowledge Check

  • According to Bohr's theory, which of the following transition in the hydrogen atom will give rise to the least energetic photon?

    A
    n = 6 to n = 5
    B
    n = 5 to n = 4
    C
    n = 5 to n = 3
    D
    n = 6 to n = 1
  • According to molecular orbital theory, which of the lists ranks the nitrogen species in terms of increasing bond order ?

    A
    `N_(2)^(2-)lt N_(2)^(-)lt N_(2)`
    B
    `N_(2)lt N_(2)^(2-)lt N_(2)^(-)`
    C
    `N_(2)^(-)lt N_(2)^(2-)lt N_(2)`
    D
    `N_(2)^(-)lt N_(2)lt N_(2)^(2-)`
  • According to the kinetic theory of gases

    A
    the pressure exerted by a gas is proportional to mean square velocity of the molecules
    B
    the pressure exerted by a gas is proportional to root mean square velocity of the molecules
    C
    the root mean square velocity is inversely proportional to the temperature
    D
    the mean translational KE of the molecules is directly proportional to the absolute temperature
  • Similar Questions

    Explore conceptually related problems

    According to MO theory, which of the following statements about the magnetic character and bond order is correct regarding O_(2)^(+) .

    According to the molecular orbital theory, which of the following statements about magnetic character and bond order is correct regarding O_2^+ ?

    According to MO theory which of the lists ranks the nitrogen species in terms of increasing bond order?

    According to Bohr's theory, the angular momentum of an electron in 5th orbit is:

    According to adsorption theory of catalysis, the speed of the reaction increases because