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In which of the following pairs, the two...

In which of the following pairs, the two species are isostructural :

A

`BrO_(3)^(-) and XeO_(3)`

B

`SF_(4) and XeF_(4)`

C

`SO_(3)^(2-) and NO_(3)^(-)`

D

`BF_(3) and NF_(3)`

Text Solution

Verified by Experts

The correct Answer is:
A
Both `BrO_(3)^(-) and XeO_(3)` involve `sp^(3)` hybridisation of central atom and has one lone pair of electrons. These have pyramidal shape.
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Knowledge Check

  • In which of the following pairs, the two species are not isostructural ?

    A
    `PCl_(4)^(+) and SiCl_(4)`
    B
    `PF_(5) and BrF_(5)`
    C
    `AlF_(6)^(3-) and SF_(6)`
    D
    `CO_(3)^(2-) and NO_(3)^(-)`

  • In which of the following pairs, the two species are not isostructural?

    A
    `PCl_4^(+)` and `SiCl_4`
    B
    `PF_3` and `BrF_5`
    C
    `AlF_6^(3-)` and `SF_6`
    D
    `CO_3^(2-)` and `NO_3^(-)`

  • In which of the following pairs are the two species isostructural?

    A
    `BrO_3^(-)` and `XeO_3`
    B
    `SF_4` and `XeF_4`
    C
    `SO_3^(2-)` and `NO_3^(-)`
    D
    `BF_3` and `NF_3`

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