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In which of the following pairs, the two...

In which of the following pairs, the two species are isostructural :

A

`BrO_(3)^(-) and XeO_(3)`

B

`SF_(4) and XeF_(4)`

C

`SO_(3)^(2-) and NO_(3)^(-)`

D

`BF_(3) and NF_(3)`

Text Solution

Verified by Experts

The correct Answer is:
A
Both `BrO_(3)^(-) and XeO_(3)` involve `sp^(3)` hybridisation of central atom and has one lone pair of electrons. These have pyramidal shape.
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Knowledge Check

  • In which of the following pairs, the two species are not isostructural ?

    A
    `PCl_(4)^(+) and SiCl_(4)`
    B
    `PF_(5) and BrF_(5)`
    C
    `AlF_(6)^(3-) and SF_(6)`
    D
    `CO_(3)^(2-) and NO_(3)^(-)`

  • In which of the following pairs, the two species are not isostructural?

    A
    `PCl_4^(+)` and `SiCl_4`
    B
    `PF_3` and `BrF_5`
    C
    `AlF_6^(3-)` and `SF_6`
    D
    `CO_3^(2-)` and `NO_3^(-)`

  • In which of the following pairs are the two species isostructural?

    A
    `BrO_3^(-)` and `XeO_3`
    B
    `SF_4` and `XeF_4`
    C
    `SO_3^(2-)` and `NO_3^(-)`
    D
    `BF_3` and `NF_3`
    • MODERN PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-OBJECTIVE TYPE QUESTIONS (B. MULTIPLE CHOICE QUESTIONS)
    1. In which of the following pairs, the two species are isostructural :

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    2. The correct order of C-O bond length among CO, CO(3)^(2-), CO(2) is

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    3. According to MO theory which of thhe following lists makes the nitroge...

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    4. In which of the following molecular/ions BF(2),NO(2)^(-),NH(2) and H(...

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    5. In which one of the following species , the central atom has the tuype...

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    6. Which of the following species does not exist under normal condition...

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    7. Among the following molecules : SO(2),SF(4) ,ClF(3) ,BrF(5) , and XeF(...

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    8. Which of the following has the minimum bond length ?

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    9. Which of the two ions from the list given below that have the geometry...

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    10. The pair of species with the same bond order is :

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    11. Which of the following species contains three bond pairs and one lone ...

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    12. Which of the following pairs is isostractural (i.e having the same sha...

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    13. Bond order of 1.5 is shown by:

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    14. Which of the following is a polar molecule

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    15. Which of the following is paramagnetic?

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    16. Which one of the following molecules contains no pi - bond ?

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    17. The bond orders for O(2)^(+) and C(2) respectively are

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    18. Which of the following molecules has the maximum dipole moment ?

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    19. Which of the following species has plane tringular shape ?

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    20. Which of the following sets of molecules contains the same number of l...

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