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Most of the polyatomic molecules except ...

Most of the polyatomic molecules except a few such as `CO_(2)` and `CS_(2)` are linear or angular with a bond angle generally somewhat greater than `90^(@)` A bond angle is defined as the angle between the direction of two covalent bonds Since the atoms in molecules are in constant motion with respect to each other they are not expected to have a fixed value of bond angle Repulsion between non-bonded atoms alone does not provide an adequate explanation Hybridisation of bonding orbitals an adequate explanation Hybridisation of bonding orbitals also plays a very important role in detrmining the value of bond angle It has been observed that in hybridisation as the s-character of hybrid orbital increases the bond angle increases
Which of the following hybridisation may have more than one type of bond angle ? .

A

The hybridised orbitals are always equivalent in energy and shape.

B

sp hybridised orbitals has more s - character than `sp^(2)` hybridised orbital.

C

Promotion of electron is essential condition prior to hybridisation.

D

The hybridized orbitals are directed in space in some preferred directions to have minimum repulsion between electron pairs.

Text Solution

Verified by Experts

The correct Answer is:
C

Promotion is not essential condition prior to hybridisation.
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Knowledge Check

  • Most of the polyatomic molecules except a few such as CO_(2) and CS_(2) are linear or angular with a bond angle generally somewhat greater than 90^(@) A bond angle is defined as the angle between the direction of two covalent bonds Since the atoms in molecules are in constant motion with respect to each other they are not expected to have a fixed value of bond angle Repulsion between non-bonded atoms alone does not provide an adequate explanation Hybridisation of bonding orbitals an adequate explanation Hybridisation of bonding orbitals also plays a very important role in detrmining the value of bond angle It has been observed that in hybridisation as the s-character of hybrid orbital increases the bond angle increases Which of the following have highest bond angle ? .

    A
    `H_(2)S`
    B
    `H_(2)Te`
    C
    `H_(2)Se`
    D
    All have same bond angle
  • Most of the polyatomic molecules except a few such as CO_(2) and CS_(2) are linear or angular with a bond angle generally somewhat greater than 90^(@) A bond angle is defined as the angle between the direction of two covalent bonds Since the atoms in molecules are in constant motion with respect to each other they are not expected to have a fixed value of bond angle Repulsion between non-bonded atoms alone does not provide an adequate explanation Hybridisation of bonding orbitals an adequate explanation Hybridisation of bonding orbitals also plays a very important role in detrmining the value of bond angle It has been observed that in hybridisation as the s-character of hybrid orbital increases the bond angle increases In P_(4) molecule phosphorous atoms are tetrahedrally arranged The angle P-P-P in the molecule is .

    A
    `108^(@)`
    B
    `120^(@)`
    C
    `60^(@)`
    D
    `180^(@)`
  • In Which of the following is the angle between the two covalent bonds is the greatest?

    A
    `CO_(2)`
    B
    `CH_(4)`
    C
    `NH_(3)`
    D
    `H_(2)O`
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