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For the equilibrium reaction 2NO2(g) h...

For the equilibrium reaction
`2NO_2(g) hArr N_2O_4(g)` + 60.0 kJ the increase in temperature

A

favours the formation of `N_2O_4`

B

favours the decomposition of `N_2O_4`

C

does not effect the equilibrium

D

stops the reaction.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the equilibrium reaction \(2NO_2(g) \rightleftharpoons N_2O_4(g) + 60.0 \, \text{kJ}\) and the effect of increasing temperature, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction and its Enthalpy Change**: The given reaction is: \[ 2NO_2(g) \rightleftharpoons N_2O_4(g) + 60.0 \, \text{kJ} \] Here, the enthalpy change (\( \Delta H \)) is positive, indicating that the reaction is endothermic. **Hint**: Remember that a positive \( \Delta H \) means heat is absorbed during the reaction. 2. **Apply Le Chatelier's Principle**: According to Le Chatelier's Principle, if a system at equilibrium is subjected to a change in temperature, the equilibrium will shift in the direction that counteracts that change. Since the reaction is endothermic, increasing the temperature will favor the formation of products. **Hint**: Think of temperature as a reactant in endothermic reactions; increasing it pushes the equilibrium towards the products. 3. **Determine the Direction of the Shift**: In this case, increasing the temperature will shift the equilibrium to the right, favoring the formation of \(N_2O_4\). **Hint**: Visualize the equilibrium as a balance; adding heat (temperature) will tip the balance towards the side that absorbs heat (the products). 4. **Conclusion**: As a result of the temperature increase, the concentration of \(N_2O_4\) will increase while the concentration of \(NO_2\) will decrease. **Hint**: The key takeaway is that for endothermic reactions, increasing temperature increases the yield of products. ### Final Answer: The increase in temperature will lead to an increase in the formation of \(N_2O_4\).

To solve the question regarding the equilibrium reaction \(2NO_2(g) \rightleftharpoons N_2O_4(g) + 60.0 \, \text{kJ}\) and the effect of increasing temperature, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction and its Enthalpy Change**: The given reaction is: \[ 2NO_2(g) \rightleftharpoons N_2O_4(g) + 60.0 \, \text{kJ} ...
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Knowledge Check

  • For the equilibrium 2NO_(2)(g)hArrN_(2)O_(4)(g) + 14.6 Kcal the increase in temperature would

    A
    Favour the formation of `N_(2)O_(4)`
    B
    Favour the decomposition of `N_(2)O_(4)`
    C
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    D
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    B
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    C
    `23.0`
    D
    20
  • For the reaction : 2SO_(2)(g)+O_(2)(g) hArr2SO_(3)(g),DeltaH=ve . An increase in temperature shows:

    A
    more dissociation of `SO_(3)` and a decreases in `K_(c)`
    B
    less dissociation of `SO_(3)` and an increases in `K_(c)`
    C
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    D
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