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For the equilibrium reaction 2NO2(g) h...

For the equilibrium reaction
`2NO_2(g) hArr N_2O_4(g)` + 60.0 kJ the increase in temperature

A

favours the formation of `N_2O_4`

B

favours the decomposition of `N_2O_4`

C

does not effect the equilibrium

D

stops the reaction.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the equilibrium reaction \(2NO_2(g) \rightleftharpoons N_2O_4(g) + 60.0 \, \text{kJ}\) and the effect of increasing temperature, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction and its Enthalpy Change**: The given reaction is: \[ 2NO_2(g) \rightleftharpoons N_2O_4(g) + 60.0 \, \text{kJ} \] Here, the enthalpy change (\( \Delta H \)) is positive, indicating that the reaction is endothermic. **Hint**: Remember that a positive \( \Delta H \) means heat is absorbed during the reaction. 2. **Apply Le Chatelier's Principle**: According to Le Chatelier's Principle, if a system at equilibrium is subjected to a change in temperature, the equilibrium will shift in the direction that counteracts that change. Since the reaction is endothermic, increasing the temperature will favor the formation of products. **Hint**: Think of temperature as a reactant in endothermic reactions; increasing it pushes the equilibrium towards the products. 3. **Determine the Direction of the Shift**: In this case, increasing the temperature will shift the equilibrium to the right, favoring the formation of \(N_2O_4\). **Hint**: Visualize the equilibrium as a balance; adding heat (temperature) will tip the balance towards the side that absorbs heat (the products). 4. **Conclusion**: As a result of the temperature increase, the concentration of \(N_2O_4\) will increase while the concentration of \(NO_2\) will decrease. **Hint**: The key takeaway is that for endothermic reactions, increasing temperature increases the yield of products. ### Final Answer: The increase in temperature will lead to an increase in the formation of \(N_2O_4\).

To solve the question regarding the equilibrium reaction \(2NO_2(g) \rightleftharpoons N_2O_4(g) + 60.0 \, \text{kJ}\) and the effect of increasing temperature, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction and its Enthalpy Change**: The given reaction is: \[ 2NO_2(g) \rightleftharpoons N_2O_4(g) + 60.0 \, \text{kJ} ...
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Knowledge Check

  • For the equilibrium 2NO_(2)(g)hArrN_(2)O_(4)(g) + 14.6 Kcal the increase in temperature would

    A
    Favour the formation of `N_(2)O_(4)`
    B
    Favour the decomposition of `N_(2)O_(4)`
    C
    Not alter the equilibrium
    D
    Stop the reaction
  • For the following equilibrium reaction , N_2O_4(g) hArr 2NO_2(g) NO_2 is 50% of total volume at given temperature . Hence vapour density of the equilibrium mixture is

    A
    34.5
    B
    25
    C
    `23.0`
    D
    20
  • For the reaction : 2SO_(2)(g)+O_(2)(g) hArr2SO_(3)(g),DeltaH=ve . An increase in temperature shows:

    A
    more dissociation of `SO_(3)` and a decreases in `K_(c)`
    B
    less dissociation of `SO_(3)` and an increases in `K_(c)`
    C
    more dissociation of `SO_(3)` and an increase in `K_(c)`
    D
    less dissociation of `SO_(3)` and a decrease in `K_(c)`
  • MODERN PUBLICATION-EQUILIBRIUM-Objective A.(MCQs)
    1. For the equilibrium reaction 2NO2(g) hArr N2O4(g) + 60.0 kJ the incr...

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    2. Which of the following favours the reverse reaction in chemical equili...

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    3. When hydrochloric aicd is addded to cobalt and nitrate solution at roo...

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    4. In the equilibrium, H3PO4 + H2O hArr H2PO4^(-) + H3O^(+) the equi...

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    5. In the dissociation of PCl(5) as PCl(5)(g) hArr PCl(3)(g)+Cl(2)(g) ...

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    6. CaCO3(s) hArr CaO(s) + CO2(g), DeltaH=110 kJ The pressure of CO2 :

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    7. Kp for the reaction: CO2(g) + H2 (g) hArr CO(g) + H2O(g) is found to ...

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    8. An equilibrium mixture for the reaction 2H2S (g) hArr 2H2(g)+S2(g) had...

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    9. In the system A((s))hArr2B((g))+3C((g)), if the concentration of C at ...

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    10. In a reversible chemical reaction having two reactants in equilibrium,...

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    11. For the reaction CH4(g) + 2O2(g) hArr CO2(g) + 2H2O(l) , DeltarH=-17...

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    12. In the reaction , A(s) +B(g) + "heat" hArr 2C(s) + 2D(g) at equili...

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    13. For the reversible reaction N(2)(g)+3H(2)(g)hAr2NH(3)(g) at 500^(@...

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    14. For the reaction , CO(g)+Cl(g)hArrCOCl2(g) then Kp//Kc is equal to :

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    15. The equilibrium constant (K(p)) for the decomposition of gaseous H(2)O...

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    16. One mole of N(2)O(4) gas at 300 K is kept in a closed container at 1 a...

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    17. For the dissociation reaction N(2)O($) (g)hArr 2NO(2)(g), the degree o...

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    18. The pH of a solution is 5.9. If the hydrogen ion concentration in decr...

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    19. When 20 mL M//20 NaOH is added to 10 ml of M//10 HCl. The resulting ha...

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    20. Ka for CH3COOH is 1.8xx10^(-5) and Kb for NH4OH is 1.8xx10^(-5) The pH...

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