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For the sparingly soluble salts, an equi...

For the sparingly soluble salts, an equilibrium is established between the undissolved solid unit and ions of the dissolved salt. For a solution of the salt like `A_x B_y`.
`A_x B_y =xA^(y+)+yB^(x-)`
`K_(sp)=[A^(y+)]^x [B^(x-)]^y`
For precipitation to occur , the ionic product must be greater than `K_(sp)`.
The solubility of `A_2X_3` is y mol `dm^(-3)` . Its solubility product is

A

`6y^4`

B

`64y^4`

C

`36y^5`

D

`108y^5`

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The correct Answer is:
To find the solubility product (Ksp) of the sparingly soluble salt \( A_2X_3 \), we will follow these steps: ### Step 1: Write the Dissociation Equation The dissociation of the salt \( A_2X_3 \) in water can be represented as: \[ A_2X_3 (s) \rightleftharpoons 2A^{3+} (aq) + 3X^{2-} (aq) \] ### Step 2: Determine the Molar Solubility Let the solubility of \( A_2X_3 \) be \( y \) mol/dm³. This means that when \( A_2X_3 \) dissolves, it produces: - \( 2y \) mol/dm³ of \( A^{3+} \) - \( 3y \) mol/dm³ of \( X^{2-} \) ### Step 3: Write the Expression for Ksp The solubility product \( K_{sp} \) is defined as: \[ K_{sp} = [A^{3+}]^2 [X^{2-}]^3 \] Substituting the concentrations from the dissociation: \[ K_{sp} = (2y)^2 (3y)^3 \] ### Step 4: Simplify the Expression Calculating the expression: \[ K_{sp} = (2y)^2 \cdot (3y)^3 = 4y^2 \cdot 27y^3 = 108y^5 \] ### Step 5: Final Result Thus, the solubility product \( K_{sp} \) of \( A_2X_3 \) is: \[ K_{sp} = 108y^5 \]

To find the solubility product (Ksp) of the sparingly soluble salt \( A_2X_3 \), we will follow these steps: ### Step 1: Write the Dissociation Equation The dissociation of the salt \( A_2X_3 \) in water can be represented as: \[ A_2X_3 (s) \rightleftharpoons 2A^{3+} (aq) + 3X^{2-} (aq) \] ...
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Knowledge Check

  • The solubility of A_(2)X_(3) is y mol dm^(-3) . Its solubility product is

    A
    `6 y^(4)`
    B
    `64 y^(4)`
    C
    `36 y^(5)`
    D
    `108 y^(5)`
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    A
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    B
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    C
    `36 y^(5)`
    D
    `108 y^(5)`
  • the solubility of A_(2)B_(3) is y mol dm^(-3) . Its solubility product is

    A
    `6y^(4)`
    B
    `64y^(4)`
    C
    `36Y^(5)`
    D
    `108y^(5)`
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