Home
Class 11
CHEMISTRY
From the following data, calculate the e...

From the following data, calculate the enthalpy change for the combustion of cyclopropane at 298 K. The enthalpy of formation of `CO_(2)(g), H_(2)O(l)` and propene (g) are - 393.5, -285.8 and 20.42 kJ ` "mol"^(-1)` respectively.The enthalpy of isomerisation of cyclopropane to propene is `-33.0 kJ "mol"^(-1)`.

Text Solution

Verified by Experts

The given equations are :
(i) `C(s) + O_(2)(g) to CO_(2)(g) DeltaH = -393.5 kJ`
(ii) `H_(2)(g) + 1/2 O_(2)(g) to H_(2)O(l) DeltaH = -285.8 kJ`
(iii) `3C(s) + 3H_(2)(g) to C_(3)H_(6)(g) DeltaH = 20.42 kJ`
(iv)
The required equation(v) can be obtained by multiplying equation(i) and (ii) by 3 and adding these, then subtracting equation(ii) from these and adding equation(iv), i.e
`DeltaH = [Eq.(i) xx 3] + [Eq.(ii) xx 3] - [Eq.(iii)] + [Eq.(iv)]`
`= (-395.5 xx 3)+(-285.8 xx 3) - (20.42) + (-33.0)`
` = -2091.32 kJ`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    MODERN PUBLICATION|Exercise Conceptual Questions -1|19 Videos
  • THERMODYNAMICS

    MODERN PUBLICATION|Exercise Conceptual Questions - 2|17 Videos
  • THERMODYNAMICS

    MODERN PUBLICATION|Exercise Practice Problems|65 Videos
  • STRUCTURE OF ATOM

    MODERN PUBLICATION|Exercise Unit Practice Test|13 Videos

Similar Questions

Explore conceptually related problems

From the following data, calculate the enthalpy change for the combustion of cyclopropane at 298K . The enthalpy of formation of CO_(2(g)),H_(2)O_((l)) and Propen e_((g)) are -393,-285.8 and 20.42 kJ mol^(-1) respectively. The enthalpy of isomerisation of cyclopropane to propene is -33.0kJ mol^(-1)

The enthalpies of formation of CO and CO_(2) are -110.5 KJ mol^(-1) and -393.5 KJ mol^(-1) respectively. The enthalpy of combustion of carbon monoxide is

Calculate the standard enthalpy of combustion of CH_(4) , it standard enthalpies of formation of CH_(4(g)),H_(2)O_((l)), and CO_(2(g)) are -74.81kJ mol^(-1), -285.83kJ mol^(-1) and -393.51kJ mol^(-1) respectively.

The enthalpies of formation of CO_(2(g)), H_(2)O_((l)) and C_(2)H_(4(g)) are respectively -393.5, -286 and +52.3 kJ mol^(-1) the enthalpy change for the combustion of C_(2)H_(4(g)) is

Calculate the standard enegry change for the reaction: OF_(2)(g) +H_(2)O(g) rarr O_(2)(g) +2HF(g) at 298K The standard enthalpies of formation of OF_(2)(g), H_(2)O(g) , and HF(g) are +20, -250 , and -270 kJ mol^(-1) , respectively.

Calculate the enthalpy of formation of acetic acid (CH_(3)COOH) if its enthalpy of combustion is 867 kJ mol^(-1) .The enthalpies of fromation of CO_(2)(g) and H_(2)O(l) are -393.5 and -285.9 kJ mol^(-1) respectively.