Name the following halides according to IUPAC system and classify them asalkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
(i) `(CH_(3))_(2)CHCH(Cl)CH_(3) , (ii) CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))Cl`
(iii) `CH_(3)CH_(2)C(CH_(3))_(2)CH_(2)I , (iv) (CH_(3))_(3)C CH_(2)CH(Br)C_(6)H_(5)`
(v) `CH_(3)CH(CH_(3))CH(Br)CH_(3) , (vi) CH_(3)C(C_(2)H_(5))_(2)CH_(2)Br`
`(vii) CH_(3)C(Cl)(C_(2)H_(5))CH_(2)CH_(3) , (viii) CH_(3)CH=C(Cl)CH_(2)CH(CH_(3))_(2)`
(ix) `CH_(3)CH=CHC(Br)(CH_(3))_(2) (x) p-ClC_(6)H_(4)CH_(2)CH(CH_(3))_(2)`
(xi) `m-ClCH_(2)C_(6)H_(4)CH_(2)C(CH_(3))_(3) , "(xii)" o-Br-C_(6)H_(4)CH(CH_(3))CH_(2)CH_(3)`
Name the following halides according to IUPAC system and classify them asalkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
(i) `(CH_(3))_(2)CHCH(Cl)CH_(3) , (ii) CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))Cl`
(iii) `CH_(3)CH_(2)C(CH_(3))_(2)CH_(2)I , (iv) (CH_(3))_(3)C CH_(2)CH(Br)C_(6)H_(5)`
(v) `CH_(3)CH(CH_(3))CH(Br)CH_(3) , (vi) CH_(3)C(C_(2)H_(5))_(2)CH_(2)Br`
`(vii) CH_(3)C(Cl)(C_(2)H_(5))CH_(2)CH_(3) , (viii) CH_(3)CH=C(Cl)CH_(2)CH(CH_(3))_(2)`
(ix) `CH_(3)CH=CHC(Br)(CH_(3))_(2) (x) p-ClC_(6)H_(4)CH_(2)CH(CH_(3))_(2)`
(xi) `m-ClCH_(2)C_(6)H_(4)CH_(2)C(CH_(3))_(3) , "(xii)" o-Br-C_(6)H_(4)CH(CH_(3))CH_(2)CH_(3)`
(i) `(CH_(3))_(2)CHCH(Cl)CH_(3) , (ii) CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))Cl`
(iii) `CH_(3)CH_(2)C(CH_(3))_(2)CH_(2)I , (iv) (CH_(3))_(3)C CH_(2)CH(Br)C_(6)H_(5)`
(v) `CH_(3)CH(CH_(3))CH(Br)CH_(3) , (vi) CH_(3)C(C_(2)H_(5))_(2)CH_(2)Br`
`(vii) CH_(3)C(Cl)(C_(2)H_(5))CH_(2)CH_(3) , (viii) CH_(3)CH=C(Cl)CH_(2)CH(CH_(3))_(2)`
(ix) `CH_(3)CH=CHC(Br)(CH_(3))_(2) (x) p-ClC_(6)H_(4)CH_(2)CH(CH_(3))_(2)`
(xi) `m-ClCH_(2)C_(6)H_(4)CH_(2)C(CH_(3))_(3) , "(xii)" o-Br-C_(6)H_(4)CH(CH_(3))CH_(2)CH_(3)`
Text Solution
Verified by Experts
(i) `overset(4)CH_(3)-underset(CH_(3))underset(|)(overset(3)CH)underset(Cl)underset(|)(overset(2)CH)overset(1)CH_(3)` : 2-Chloro-3-methylbutane (`2^(@)`- alkyl halide)
(ii) `overset(6)CH_(3)overset(5)CH_(2)underset(CH_(3))underset(|)(overset(4)CH)underset(C_(2)H_(5))underset(|1,2)(overset(3}CH)-Cl` : 3-Chloro-4-methylbutane (`2^(@)`- alkyl halide)
(iii) `overset(4)CH_(3)overset(3)CH_(2)underset(CH_(3))underset(|)overset(CH_(3))overset(2|)C overset(1)CH_(2)I` : 1-Iodo-2, 2-dimethylbutane(`1^(@)`-alkyl halide)
(iv) `overset(4)CH_(3)underset(CH_(3))underset(|)overset(CH_(3))overset(3|)Coverset(2)CH_(2)underset(Br)underset(|)(overset(1)CH)-C_(6)H_(5)` : 1-Bromo-3, 3-dimethyl-1-phenylbutane(`2^(@)`-benxylic halide)
(v) `overset(4)CH_(3)underset(CH_(3))underset(|)overset(3)CH underset(Br)underset(|)overset(2)CH overset(1)CH_(3)` : 2-Bromo-3-methylbutane(`2^(@)` -alkyl halide)
(vi) `CH_(3)underset(overset(3)CH_(2)overset(4)CH_(3))underset(|)overset(C_(2)H_(5))overset(2|)C overset(1)CH_(2)Br` : 1-Bromo-2-ethyl-2methylbutane(`1^(@)`-alkyl halide)
(vii) `CH_(3)underset(Cl)underset(|)overset(overset(1,2)C_(2)H_(5))overset(3|)Coverset(4)CH_(2)overset(5)CH_(3)` :3-Chloro-3-methylpentane (`3^(@)`-alkyl halide)
(viii) `overset(1)CH_(3)overset(2)CH=underset(Cl)underset(|)overset(3)C overset(4)CH_(2)underset(CH_(3))underset(|)overset(5)CH-overset(6)CH_(3)` : 3-Chloro-5-methylhex-2-ene (vinylic halide)
(ix) `overset(1)CH_(3)overset(2)CH=overset(3)CHunderset(Br)underset(|)overset(CH_(3))overset(4|)C-overset(5)CH_(3)` : 4-Bromo-4-methylpent-2-ene (allylic halide)
(ii) `overset(6)CH_(3)overset(5)CH_(2)underset(CH_(3))underset(|)(overset(4)CH)underset(C_(2)H_(5))underset(|1,2)(overset(3}CH)-Cl` : 3-Chloro-4-methylbutane (`2^(@)`- alkyl halide)
(iii) `overset(4)CH_(3)overset(3)CH_(2)underset(CH_(3))underset(|)overset(CH_(3))overset(2|)C overset(1)CH_(2)I` : 1-Iodo-2, 2-dimethylbutane(`1^(@)`-alkyl halide)
(iv) `overset(4)CH_(3)underset(CH_(3))underset(|)overset(CH_(3))overset(3|)Coverset(2)CH_(2)underset(Br)underset(|)(overset(1)CH)-C_(6)H_(5)` : 1-Bromo-3, 3-dimethyl-1-phenylbutane(`2^(@)`-benxylic halide)
(v) `overset(4)CH_(3)underset(CH_(3))underset(|)overset(3)CH underset(Br)underset(|)overset(2)CH overset(1)CH_(3)` : 2-Bromo-3-methylbutane(`2^(@)` -alkyl halide)
(vi) `CH_(3)underset(overset(3)CH_(2)overset(4)CH_(3))underset(|)overset(C_(2)H_(5))overset(2|)C overset(1)CH_(2)Br` : 1-Bromo-2-ethyl-2methylbutane(`1^(@)`-alkyl halide)
(vii) `CH_(3)underset(Cl)underset(|)overset(overset(1,2)C_(2)H_(5))overset(3|)Coverset(4)CH_(2)overset(5)CH_(3)` :3-Chloro-3-methylpentane (`3^(@)`-alkyl halide)
(viii) `overset(1)CH_(3)overset(2)CH=underset(Cl)underset(|)overset(3)C overset(4)CH_(2)underset(CH_(3))underset(|)overset(5)CH-overset(6)CH_(3)` : 3-Chloro-5-methylhex-2-ene (vinylic halide)
(ix) `overset(1)CH_(3)overset(2)CH=overset(3)CHunderset(Br)underset(|)overset(CH_(3))overset(4|)C-overset(5)CH_(3)` : 4-Bromo-4-methylpent-2-ene (allylic halide)
|
Topper's Solved these Questions
HALOALKANES AND HALOARENES
MODERN PUBLICATION|Exercise NCERT Textbooks Exercise|21 VideosHALOALKANES AND HALOARENES
MODERN PUBLICATION|Exercise NCERT examplar Problems (Multiple Choice Questions (Type-I))|31 VideosHALOALKANES AND HALOARENES
MODERN PUBLICATION|Exercise NCERT In-text Questions|8 VideosEQUILIBRIUM
MODERN PUBLICATION|Exercise Unit Practice Test|13 VideosHYDROCARBONS
MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|15 Videos
Similar Questions
Explore conceptually related problems
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides. (i) (CH_(3))_(2)CHCH(Cl)CH_(3) (ii) CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))Cl (iii) CH_(3)CH_(2)C(CH_(3))_(2)CH_(2)I (iv) (CH_(3))_(3)C CH_(2)CH(Br)C_(6)H_(5) (v) CH_(3)CH(CH_(3))CH(Br)CH_(3) (vi) CH_(3)C(C_(2)H_(5))_(2)CH_(2)Br CH_(3)C(Cl)(C_(2)H_(5))CH_(2)CH_(3) (viii) CH_(3)CH=C(Cl)CH_(2)CH(CH_(3))_(2) (ix) CH_(3)CH=CHC(Br)(CH_(3))_(2) (x) p-ClC_(6)H_(4)CH_(2)CH(CH_(3))_(2) (xi) m-ClCH_(2)C_(6)H_(4)CH_(2)C(CH_(3))_(3) (xii) o-Br-C_(6)H_(4)CH(CH_(3))CH_(2)CH_(3) .
Name the following compounds according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary) vinyl or aryl halides. (i). (CH_(3))_(2)CHCH(Cl)CH_(3) (ii). CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))Cl (iii). CH_(3)CH_(2)C(CH_(3))_(2)CH_(2)I (iv). CH_(3)C(Cl)(C_(2)H_(5))CH_(2)CH_(3) (v). CH_(3)gtC(C_(2)H_(5))CH_(2)Br (vi). CH_(3)CH=C(Cl)CH_(2)CH(CH_(3))_(2) (vii). CH_(2)=CH-CH_(2)-Br (viii). CH_(3)CH=CHC(Br)(CH_(3))_(2) . (ix). m-ClCH_(2)C_(6)H_(4)CH_(2)C(CH_(3))_(3) (x). o-BrC_(6)H_(4)CH(CH_(3))CH_(2)CH_(3) (xi). (CH_(3))_(3)C CH_(2)CH(Br)C_(6)H_(5) (xii). p-ClC_(6)H_(4)CH_(2)CH(CH_(3))_(2) .
Knowledge Check
The correct IUPAC name of CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))_(2) is
The correct IUPAC name of CH_(3)CH_(2)CH(CH_(3))CH(C_(2)H_(5))_(2) is
A
4-Ethyl-3-methylhexane
B
3-Ethyl-4-methylhexane
C
3-Methyl-4-ethylhexane
D
2-Isopentylbutane.
Similar Questions
Explore conceptually related problems
Classify the following as alkyl, vinyl, allyl or aryl halides : (i) H_(2)C=CHCHI_(2) (ii) CH_(3)CH=CFCH_(2)CH_(3) (iii) (iv) (CH_(3))_(2)C ClCH_(2)CH_(3) (v) (CH_(3))_(2)C=CHCH_(2)Br (vi) C_(6)H_(5)Br
Classify the following as alkyl, vinyl, allyl or aryl halides : (i) H_(2)C=CHCHI_(2) (ii) CH_(3)CH=CFCH_(2)CH_(3) (iii) (iv) (CH_(3))_(2)C ClCH_(2)CH_(3) (v) (CH_(3))_(2)C=CHCH_(2)Br (vi) C_(6)H_(5)Br
Name the following compounds according to IUPAC system of nomenclature. (i) CH_(3)CH(CH_(3))CH_(2)CH_(2)CHO , (ii) CH_(3)CH_(2)COCH(C_(2)H_(5))CH_(2)CH_(2)Cl (iii) CH_(3)CH=CHCHO (iv) CH_(3)COCH_(2)COCH_(3) (v) CH_(3)CH(CH_(3))CH_(2)C(CH_(3))_(2)COCH_(3) (vi). (CH_(3))_(3)C CH_(2)COOH (vii) OHC C_(6)H_(4)CHO-p
Write IUPAC names of the following compounds : (a) CH_(3)CH(Cl)CH(Br)CH_(3) (b) CHF_(2)CBrClF (c) ClCH_(2)C-=C CH_(2)Br (d) (C Cl_(3))_(3)C Cl (e) CH_(3)C(p-ClC_(6)H_(4))_(2)CH(Br)CH_(3) (f) (CH_(3))_(3)C CH=C(Cl)C_(6)H_(4)I-p (g) CH_(3)CHCl(CH_(2))_(2)C Cl_(2)C_(2)H_(5)
Arrange the following compounds in increasing order of S_(N)1 reactivity. (i) ClCH_(2)CH = CHCH_(2)CH_(3) , CH_(3)C(Cl) = CHCH_(2)CH_(3) , CH_(3)CH = CHCH_(2)CH_(2)Cl , CH_(3)CH = CHCH(Cl)CH_(3) (ii) CH_(3)CH_(2)Br, CH_(2) = CHCH(Br)CH_(3) , CH_(2) = CHBr, CH_(3)CH(Br)CH_(3) (iii) (CH_(3))_(3)C Cl , C_(6)H_(5)C(CH_(3))_(2)Cl , (CH_(3))_(2)CHCl , CH_(3)CH_(2)CH_(2)Cl
Predict the order of reactivity of the following compounds in dehydrohalogenation: (a) CH_(3)CH_(2)CH_(2)CH_(2)Cl, (CH_(3))_(2)CHCH_(2)Cl, (CH_(3))_(2)CH-CH_(2)Br, CH_(3)CH(Br)CH_(2)CH_(3), (CH_(3))_(3)C-Br (b) CH_(3)CH(Br)CH_(3), CH_(3)CH_(2)CH_(2)Br, (CH_(3))_(2)CHCH_(2)Br, (CH_(3))_(2)C CH_(2)Br
How many of the following alkyl halides would react by S_(N^(1)) mechanism? CH_(3)Br,CH_(3)CH_(2)Br,CH_(3)CH_(2)CH_(2)I,(CH_(3))_(3)CBr,BrCH_(3)CH=CH_(2),C_(6)H_(5)CH_(2)Br,(CH_(3))_(3)C CH_(2)Br,C_(6)H_(5)CHBrCH_(3),CH_(3)CH=CHCH_(2)Cl . .