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(i)Which one out of Fe^(2+)and Fe^(3+) i...

(i)Which one out of `Fe^(2+)`and `Fe^(3+)` ions is more paramagnetic and why
(ii)Which of the following ions are expected to be coloured and why`Fe(_2+), Mn^(2+), Cr^(3+), Cu(+) Sc^(3+), Ti^(4+)`

Text Solution

Verified by Experts

`Fe^(3+)` is more paramagnetic than `(Fe^(2+)` as `Fe^(3+)`has five unpaired electrons while `Fe^(2+)` possesses four unpaired electrons
The ions of transition elements which possess unpaired electrons show a characteristic colour, due to d-d transition`(n-1)d^(0)or(N-1)^(10)` configuration does not involve d-d transition and hence, is colourless. `Fe^(2+), Mn^(2+)` and `Cr^(3+)` are coloured while `Cu^(+), Sc^(3+)` and `Ti^(4+)` are colourless
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(i)Which one out of Fe^(2+) and Fe^(3+) ions is more paramagnetic and why (ii)Which of the following ions are expected to becoloured and why Fe^(2+), Mn^(2+), Cr^(3+), Cu^(+) Sc^(3+), Ti^(4+)

Out of Fe^(2+) and Fe^(3+) which is more paramagnetic and why?

Knowledge Check

  • Which of these ions is expected to be coloured in aqueous solution? (P) Fe^(3+) (Q) Ni^(2+) (R) Al^(3+)

    A
    P only
    B
    R only
    C
    P and Q
    D
    P,Q and R
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    A
    [I] only
    B
    [III] only
    C
    [I] and [II] only
    D
    [I],[II] and [III]
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