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CH(3)-CH=CH-CHO overset(A)to CH(3)-CH=CH...

`CH_(3)-CH=CH-CHO overset(A)to CH_(3)-CH=CH-CH_(3)`
The best suitable reagent A is

A

`C_(3)H_(8)S_(2)//H_(2)//Ni`

B

`N_(2)H_(4)//KOH`

C

`Zn-Hg//conc.HCl`

D

HI/P(red)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the best suitable reagent (A) that converts the compound CH₃-CH=CH-CHO into CH₃-CH=CH-CH₃. ### Step-by-Step Solution: 1. **Identify the Reactant and Product:** - The reactant is CH₃-CH=CH-CHO (an aldehyde with a double bond). - The product is CH₃-CH=CH-CH₃ (an alkene). 2. **Analyze the Functional Groups:** - In the reactant, we have a carbonyl group (C=O) as part of the aldehyde (CHO). - In the product, this carbonyl group is converted to a methylene group (CH₂), indicating a reduction of the carbonyl group. 3. **Determine the Type of Reaction:** - The conversion of the carbonyl group (CHO) to a methylene group (CH₂) is a reduction reaction. - There are two common methods for reducing carbonyl groups: Clemensen reduction and Wolff-Kishner reduction. 4. **Clemensen Reduction:** - This method involves using zinc amalgam and hydrochloric acid (Zn/HCl). - However, this method is not suitable here because it is acid-sensitive and can affect the alkene present in the reactant. 5. **Wolff-Kishner Reduction:** - This method uses hydrazine (N₂H₄) in the presence of a strong base like potassium hydroxide (KOH). - This method is suitable for reducing aldehydes and ketones to alkanes without affecting double bonds. 6. **Conclusion:** - Since the reactant contains an alkene that is sensitive to acid, the Wolff-Kishner reduction is the appropriate choice to convert the aldehyde to an alkane while preserving the alkene. - Therefore, the best suitable reagent (A) is N₂H₄ in the presence of KOH. ### Final Answer: The best suitable reagent (A) is **N₂H₄ in the presence of KOH** (Wolff-Kishner reduction).
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Knowledge Check

  • Find out A, B, C , D in following reaction (1) CH_(3) - CH = CH - CHO overset(A) to CH_(3) - CH = CH - COOH (2) CH_(3) - CH = CH - CHO overset(B) to CH_(3) - CH = CH - CH_(2) - OH (3) R - COOH overset(C) to R - CH_(2) - OH (4) R - COCl overset(D) to R - CHO

    A
    `{:(1= h_(2) .Pf.BaSO_(4),2= "Ammoniacal "AgNO_(3)),(3= LiAlH_(4),4=LiAlH_(4)):}`
    B
    `{:(1=LiAlH_(4),2= LiAlH_(4)),(3=H_(2).Pd.BaSO_(4),4="Ammoniacal "AgNO_(3)):}`
    C
    `{:(1="Ammoniacal "AgNO_(3),2=LiAlH_(4)),(3=LiAlH_(4),4=H_(2)Pd +BaSO_(4)):}`
    D
    `{:(1=LiAlH_(4),2=LiAlH_(4)),(3="Ammoniacal" AgNO_(3),4=H_(2)Pd+BaSO_(4)):}`
  • CH_(3)CH_(2)-C-=N overset(X)to CH_(3)CH_(2)-CHO The reagent/s X is (are)

    A
    `SnCl_(2)//HCl,H_(2)O//`boil
    B
    `H_(2)//Pd-BaSO_(4)`
    C
    `LiAlH_(4)//`ether
    D
    `NaBH_(4)//ether,H_(3)O^(+)`
  • CH_(3)CHO+CH_(3)CHO overset(base)(rarr) CH_(3)-CH(OH)CH_(2)CHO represents ,

    A
    Aldol condensation
    B
    Cannizaro's reaction
    C
    Benzoin's condensation
    D
    Clemmension's reaction
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