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CH(3)-CH=CH-CHO overset(A)to CH(3)-CH=CH...

`CH_(3)-CH=CH-CHO overset(A)to CH_(3)-CH=CH-CH_(3)`
The best suitable reagent A is

A

`C_(3)H_(8)S_(2)//H_(2)//Ni`

B

`N_(2)H_(4)//KOH`

C

`Zn-Hg//conc.HCl`

D

HI/P(red)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the best suitable reagent (A) that converts the compound CH₃-CH=CH-CHO into CH₃-CH=CH-CH₃. ### Step-by-Step Solution: 1. **Identify the Reactant and Product:** - The reactant is CH₃-CH=CH-CHO (an aldehyde with a double bond). - The product is CH₃-CH=CH-CH₃ (an alkene). 2. **Analyze the Functional Groups:** - In the reactant, we have a carbonyl group (C=O) as part of the aldehyde (CHO). - In the product, this carbonyl group is converted to a methylene group (CH₂), indicating a reduction of the carbonyl group. 3. **Determine the Type of Reaction:** - The conversion of the carbonyl group (CHO) to a methylene group (CH₂) is a reduction reaction. - There are two common methods for reducing carbonyl groups: Clemensen reduction and Wolff-Kishner reduction. 4. **Clemensen Reduction:** - This method involves using zinc amalgam and hydrochloric acid (Zn/HCl). - However, this method is not suitable here because it is acid-sensitive and can affect the alkene present in the reactant. 5. **Wolff-Kishner Reduction:** - This method uses hydrazine (N₂H₄) in the presence of a strong base like potassium hydroxide (KOH). - This method is suitable for reducing aldehydes and ketones to alkanes without affecting double bonds. 6. **Conclusion:** - Since the reactant contains an alkene that is sensitive to acid, the Wolff-Kishner reduction is the appropriate choice to convert the aldehyde to an alkane while preserving the alkene. - Therefore, the best suitable reagent (A) is N₂H₄ in the presence of KOH. ### Final Answer: The best suitable reagent (A) is **N₂H₄ in the presence of KOH** (Wolff-Kishner reduction).
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